17909-51-2

Basic information

• Product Name: Silane, benzoyldimethylphenyl-
• CAS NO: 17909-51-2
• Molecular Formula: C15H16OSi
• Molecular Weight: 240.377
• Mol File: 17909-51-2.mol
• Article Data: 19

Chemical Properties

• CAS DataBase Reference: Silane, benzoyldimethylphenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Silane, benzoyldimethylphenyl-(17909-51-2)
• EPA Substance Registry System: Silane, benzoyldimethylphenyl-(17909-51-2)

Safety Data

• Hazardous Substances Data: 17909-51-2(Hazardous Substances Data)

Upstream product

• 98-88-4 benzoyl chloride 
• 768-33-2 phenyldimethylsilyl chloride 
• 100-44-7 benzyl chloride 
• 65-85-0 benzoic acid 
• 185990-03-8 dimethylphenyl(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)silane 
• 53639-33-1 benzoic tert-butylcarbonic anhydride 
• 93-97-0 benzoic acid anhydride 
• 19820-60-1 Benzoic trimethylacetic anhydride 
• 1548-84-1 pentafluorophenyl benzoate 
• 455-32-3 benzoyl fluoride 
• 707-07-3 orthobenzoic acid trimethyl ester 
• 3839-31-4 dimethyl(phenyl)silyl lithium 
• 22158-84-5 N-(p-Toluolsulfonyl)-benzimidsaeure-methylester 
• 884-09-3 phenyl thiobenzoate 

Downstream Products

• 648428-54-0 [dimethylphenylsilyl(phenyl)methoxy]trimethylsilane 
• 72656-47-4 ethyl (R)-3-hydroxy-3-phenylpropanoate 
• 778-24-5 Dimethyldiphenylsilane 

Relevant articles and documents

A simple method for mild oxidation of α-hydroxysilanes to provide aroylsilanes

Potassium permanganate supported onto alumina in hexane-water is a good oxidizing agent to convert α-hydroxysilanes into acylsilanes. This mild oxidation afforded aroylsilanes having electron-donating groups attached to the aromatic ring, in 70-86% yield.

Tertiary α-Silyl Alcohols by Diastereoselective Coupling of 1,3-Dienes and Acylsilanes Initiated by Enantioselective Copper-Catalyzed Borylation

An efficient synthesis of functionalized tertiary α-silyl alcohols by an enantio- and diastereoselective copper-catalyzed three-component coupling of 1,3-dienes, bis(pinacolato)diboron, and acylsilanes is reported. The reaction proceeds well with different 1,3-dienes and a broad range of aryl- as well as alkenyl- but also alkyl-substituted acylsilanes. The target compounds are formed with high regio-, diastereo-, and enantioselectivity (up to 99 % ee and d.r. >20:1) and are highly versatile synthetic building blocks.

Zinc-Catalyzed Synthesis of Acylsilanes Using Carboxylic Acids and a Silylborane in the Presence of Pivalic Anhydride

Zinc-catalyzed synthesis of acylsilanes using carboxylic acids and a silylborane has been achieved in the presence of pivalic anhydride. Various carboxylic acids were converted to the corresponding acylsilanes. The in situ formation of mixed anhydrides wa