180594-90-5

Basic information

• Product Name: 4'-Undec-10-enyloxy-biphenyl-4-carboxylic acid 4-((R)-1-methyl-non-8-enyloxy)-3-nitro-phenyl ester
• Synonyms: 4'-Undec-10-enyloxy-biphenyl-4-carboxylic acid 4-((R)-1-methyl-non-8-enyloxy)-3-nitro-phenyl ester
• CAS NO: 180594-90-5
• Molecular Weight: 641.848
• Mol File: 180594-90-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 4'-Undec-10-enyloxy-biphenyl-4-carboxylic acid 4-((R)-1-methyl-non-8-enyloxy)-3-nitro-phenyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: 4'-Undec-10-enyloxy-biphenyl-4-carboxylic acid 4-((R)-1-methyl-non-8-enyloxy)-3-nitro-phenyl ester(180594-90-5)
• EPA Substance Registry System: 4'-Undec-10-enyloxy-biphenyl-4-carboxylic acid 4-((R)-1-methyl-non-8-enyloxy)-3-nitro-phenyl ester(180594-90-5)

Safety Data

• Hazardous Substances Data: 180594-90-5(Hazardous Substances Data)

Upstream product

• 142288-39-9 (S)-dec-9-en-2-ol 
• 178110-86-6 dec-9-en-2-ol 
• 180594-88-1 Benzoic acid 4-((R)-1-methyl-non-8-enyloxy)-3-nitro-phenyl ester 
• 85721-25-1 2-(oct-7-en-1-yl)oxirane 
• 2444-21-5 (4'-benzyloxyphenyl)benzoate 
• 13985-43-8 4-hydroxy-3-nitrophenyl benzoate 
• 2444-19-1 4-hydroxyphenyl benzoate 
• 103-16-2 4-Benzyloxyphenol 
• 180594-89-2 4-[(R)-(-)-2-(9-decenyl)oxy]-3-nitrophenol 
• 151419-76-0 4'-(10-undecen-1-yloxy)-1,1'-biphenyl-4-carboxylic acid 

Downstream Products

• 180594-92-7 4'-(11-acryloyloxy-undecyloxy)-biphenyl-4-carboxylic acid 4-(9-acryloyloxy-1(R)-methyl-nonyloxy)-phenyl ester 
• 180594-91-6 4'-(11-Hydroxy-undecyloxy)-biphenyl-4-carboxylic acid 4-((R)-9-hydroxy-1-methyl-nonyloxy)-3-nitro-phenyl ester 

Relevant articles and documents

Preparation of a novel cross-linked polymer for second-order nonlinear optics

A novel cross-linked pyroelectric polymer with pronounced second-order nonlinear optical properties has been prepared. A multistep synthesis with several selective transformations including a kinetic resolution (transesterification) with the highly enantioselective Candida antarctica lipase B, yielded the monomer 4''-{(R)-(-)-2[(10-acryloyloxy)decyl]oxy}-3-nitrophenyl 4-{4'-[(11-acryloyloxy)undecyloxy]phenyl}benzoate A2c which displayed a ferroelectric chiral smectic C phase with large spontaneous polarization (175 nC/cm2). The monomer was poled and subsequently cross-linked by in-situ photopolymerization in the surface-stabilized ferroelectric liquid crystalline state. The cross-linked pyroelectric polymer exhibited an electro-optical coefficient (r22-r12) of 15-35 pm/V.