18096-82-7Relevant articles and documents
Spin crossover and paramagnetic behaviour in two-dimensional iron(II) coordination polymers with stilbazole push-pull ligands
Agust, Gloria,Gaspar, Ana Be?n,Mu?oz, M. Carmen,Lacroix, Pascal G.,Real, Jo? Antonio
, p. 1155 - 1165 (2009)
The suitability of the stilbazole pushpull ligands, 4′- dimethylaminostilbazole (DMAS) and 4′-diethylaminostilbazole (DEAS), for the construction of bimetallic FeIIAgI/AuI cyanide-based coordination polymers that exhibit s
Self-assembly of a series of thiocyanate complexes with high two-photon absorbing active in near-IR range and bioimaging applications
Li, Dandan,Zhang, Qiong,Wang, Xuchun,Li, Shengli,Zhou, Hongping,Wu, Jieying,Tian, Yupeng
, p. 175 - 183 (2015/05/13)
Abstract A series of novel complexes bearing high fluorescence quantum yields and showing the peak two-photon absorption (2 PA) cross-sections in the near-infrared region, Zn(SCN)2L2(1), [Cd(SCN)2L2]n(2), Co(SCN)2L4(3), Ni(SCN)2L4(4), [CdHgL2(SCN)4]n(5) and [MnHg(SCN)4L2]n(6), containing functional chromophore (L = (E)-(4-diethyl anilinostyryl)pyridine), were synthesized in high yields. Crystal structures of all the complexes were confirmed. Hetero-metal complexes (5, 6: L:M = 1:1) present much higher two-photon absorption (2 PA) cross-sections (σ) in comparison with those of the homo-metal complexes (L:M = 4:1 in 3 and 4, L:M = 2:1 in 1 and 2) and the free ligand (L) which may due to the fact that the hetero-metal complexes have more bridged anions (SCN-), conjugated subunits -[Hg(SCN)2M]- and -[Hg2(SCN)4M2]-. In addition, the results revealed that 2 PA response was much enhanced for the Zn(SCN)2L2 and two-photon fluorescence cell imaging experiment proved its potential application.
Pyrene-excimers-based antenna systems
Cicchi, Stefano,Fabbrizzi, Pierangelo,Ghini, Giacomo,Brandi, Alberto,Foggi, Paolo,Marcelli, Agnese,Righini, Roberto,Botta, Chiara
supporting information; experimental part, p. 754 - 764 (2009/08/07)
A series of dendrimeric compounds bearing pyrene units were synthesized to afford light-harvesting antennae based on the formation of intramolecular excimers. The synthetic plan profited from the efficiency of the Huisgen reaction, the 1,3-dipolar cycload