181265-77-0

Basic information

• Product Name: 2-bromoacetophenone t-butoxycarbonyl hydrazone
• Synonyms: 2-bromoacetophenone t-butoxycarbonyl hydrazone
• CAS NO: 181265-77-0
• Molecular Weight: 313.194
• Mol File: 181265-77-0.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 2-bromoacetophenone t-butoxycarbonyl hydrazone(CAS DataBase Reference)
• NIST Chemistry Reference: 2-bromoacetophenone t-butoxycarbonyl hydrazone(181265-77-0)
• EPA Substance Registry System: 2-bromoacetophenone t-butoxycarbonyl hydrazone(181265-77-0)

Safety Data

• Hazardous Substances Data: 181265-77-0(Hazardous Substances Data)

Upstream product

• 870-46-2 t-butoxycarbonylhydrazine 
• 70-11-1 α-bromoacetophenone 

Downstream Products

• 32119-53-2 N-methyl-N-phenacylaniline 
• 30020-98-5 N-methyl-3-phenylindole 

Relevant articles and documents

Silver(I)- and Base-Mediated formal [4+3] Cycloaddition of in Situ generated 1,2-Diaza-1,3-dienes with C,N-Cyclic Azomethine Imines: An Efficient Protocol for the Synthesis of Tetrazepine Derivatives

A silver(I)- and base-mediated formal [4+3] cycloaddition reaction of in situ generated 1,2-diaza-1,3-dienes with in situ formed C,N-cyclic azomethine imines has been developed. This protocol provided an efficient method for the synthesis of biologically important 1,2,4,5-tetrazepine derivatives with a wild substrate scope and excellent functional group tolerance in moderate to excellent yields. (Figure presented.).

Cycloaddition reactions of nitrosoalkenes, azoalkenes and nitrile oxides mediated by hydrotalcite

Mg:Al 3:1 hydrotalcite (Ht), used in catalytic quantities, promotes the generation of nitrosoalkenes, azoalkenes and nitrile oxides. These can be intercepted in situ by heterocycles and olefins in [4+2] and [3+2] cycloaddition reactions, producing dihydro