18216-74-5Relevant articles and documents
C(sp3)-H bond functionalization with styrenesviahydrogen-atom transfer to an aqueous hydroxyl radical under photocatalysis
Mori, Shogo,Saito, Susumu
supporting information, p. 3575 - 3580 (2021/06/06)
The redox-neutral addition of α-C-H bonds of acetonitrile and acetone to styrenes was enabledviathe hydrogen-atom transfer from relatively acidic and water-miscible C(sp3)-H bonds to an aqueous hydroxyl radical generated cleanly and iteratively
A hydrate salt-promoted reductive coupling reaction of nitrodienes with unactivated alkenes
Zhang, Mengmeng,Yang, Liming,Tian, Chao,Zhou, Meng,An, Guanghui,Li, Guangming
, p. 2258 - 2264 (2019/02/27)
Transition metal-catalyzed reductive coupling has emerged as a powerful method for the construction of C-C bonds. Herein, a crystalline hydrate, Na2HPO4·7H2O, has been disclosed as an effective promoter for the reductive c
A practical and catalytic reductive olefin coupling
Lo, Julian C.,Yabe, Yuki,Baran, Phil S.
supporting information, p. 1304 - 1307 (2014/02/14)
A redox-economic method for the direct coupling of olefins that uses an inexpensive iron catalyst and a silane reducing agent is reported. Thus, unactivated olefins can be joined directly to electron-deficient olefins in both intra- and intermolecular settings to generate hindered bicyclic systems, vicinal quaternary centers, and even cyclopropanes in good yield. The reaction is not sensitive to oxygen or moisture and has been performed on gram-scale. Most importantly, it allows access to many compounds that would be difficult or perhaps impossible to access using other methods.
