18648-66-3Relevant articles and documents
Highly emissive phenylene-expanded [5]radialene
Gu, Xinggui,He, Zikai,Li, Xin-Gui,Tang, Ben Zhong,Tang, Chunlin,Yu, Jie,Yu, Zhen-Qiang,Zheng, Xiaoyan
, p. 3911 - 3914 (2020)
A pentagonal macrocycle (MC5-PER) with radialene topology was facilely synthesized through a selective one-pot Suzuki-Miyaura cross-coupling reaction. The resulting product is endowed with a pentagonal architecture as revealed by its single crystal structure, which affords the smallest ring strain and the best conjugation. As tetraphenylethene subunits are embedded, MC5-PER is highly emissive in the solid state due to the aggregation-induced emission effect. Because of the flexible structure and preferable fibre-like self-assembly, the aggregate of MC5-PER displays interesting polymorphism-dependent emission and acts as a sensitive fluorescence sensor for explosives detection.
Pd-Catalyzed Coupling of N-Tosylhydrazones with Benzylic Phosphates: Toward the Synthesis of Di- or Tri-Substituted Alkenes
Zhang, Kena,Provot, Olivier,Alami, Mouad,Tran, Christine,Hamze, Abdallah
, p. 1249 - 1261 (2022/02/07)
This study shows that various di- and tri-substituted alkenes with high chemoselectivity were obtained in good to high yields by coupling N-tosylhydrazones (NTHs) with benzylic phosphates as electrophilic partners. The obtained new catalytic system consis
Effects of incorporating regioisomers and flexible rotors to direct aggregation induced emission to achieve stimuli-responsive luminogens, security inks and chemical warfare agent sensors
Adil, Laxmi Raman,Iyer, Parameswar Krishnan
, p. 7633 - 7636 (2020/07/21)
Efficient transformation of ACQ materials to AIE luminogens using simple design principles of positional isomerization and C-C bond exclusion is presented here. Consequently, the bond link, position and packing influence the photophysical properties that can be utilized in erasable secret inks, pressure sensors and chemical warfare sensors.