1882-47-9Relevant articles and documents
Improved catalytic asymmetric carbon-carbon bond formation using combinations of chiral and achiral monodentate ligands
Duursma, Ate,Pena, Diego,Minnaard, Adriaan J.,Feringa, Ben L.
, p. 1901 - 1904 (2005)
Mixtures of chiral and achiral monodentate phosphoramidite ligands lead to improved enantioselectivity in the rhodium-catalyzed boronic acid addition.
Synthesis of palladium nanoparticles using triazolium based ionic liquids: A reusable catalyst for addition of arylboronic acids to nitrostyrenes
Sundararaju, Kavya,Veeraragavan, VijayaKumar,Chidambaram, Ramesh Kumar
supporting information, p. 3000 - 3014 (2018/12/04)
Formation of stable and small-sized palladium nanoparticles of diameter 9.4 nm was accomplished by a simple heating of Pd(OAc)2 in 1-octyl-1,2,4-triazolium trifluoroacetate ionic liquid under standard atmospheric hydrogen pressure. Palladium na
Palladium-catalyzed asymmetric addition of arylboronic acids to nitrostyrenes
He, Qun,Xie, Fang,Fu, Guanghong,Quan, Mao,Shen, Chaoren,Yang, Guoqiang,Gridnev, Ilya D.,Zhang, Wanbin
supporting information, p. 2250 - 2253 (2015/05/13)
A palladium-catalyzed asymmetric addition of arylboronic acids to nitrostyrene is reported. The catalytic system employing iPr-IsoQuinox as a chiral ligand in MeOH solvent under an air atmosphere provides the chiral diarylsubstituted products in high yields with good enantioselectivities. A variety of functionalized nitrostyrenes can be used, and the method tolerates some variation in arylboronic acid scope. The stereochemical outcome can be explained using a stereochemical model.
