1883-96-1

Basic information

• Product Name: N-[(E)-phenylmethylidene]pyridin-2-amine
• Synonyms: 2-Pyridinamine, N-(phenylmethylene)-; 2-pyridinamine, N-[(1E)-phenylmethylene]-; N-(Phenylmethylene)-2-pyridinamine; N-[(E)-Phenylmethylene]pyridin-2-amine
• CAS NO: 1883-96-1
• Molecular Formula: C₁₂H₁₀N₂
• Molecular Weight: 182.2212
• Mol File: 1883-96-1.mol
• Article Data: 50

Chemical Properties

• Boiling Point: 324.162°C at 760 mmHg
• Flash Point: 149.848°C
• Density: 1.023g/cm³
• Vapor Pressure: 0mmHg at 25°C
• Refractive Index: 1.575
• CAS DataBase Reference: N-[(E)-phenylmethylidene]pyridin-2-amine(CAS DataBase Reference)
• NIST Chemistry Reference: N-[(E)-phenylmethylidene]pyridin-2-amine(1883-96-1)
• EPA Substance Registry System: N-[(E)-phenylmethylidene]pyridin-2-amine(1883-96-1)

Safety Data

• Hazardous Substances Data: 1883-96-1(Hazardous Substances Data)

Upstream product

• 504-29-0 2-aminopyridine 
• 100-52-7 benzaldehyde 
• 41855-95-2 N,N¹--α,α-diaminotoluene 
• 71-43-2 benzene 
• 27200-79-9 p-bromophenylacetaldehyde 
• 538-51-2 benzylidene phenylamine 
• 100-51-6 benzyl alcohol 
• 23574-81-4 N-(triphenylphosphoranylidene)pyridin-2-amine 
• 108-88-3 toluene 
• 108-93-0 cyclohexanol 

Downstream Products

• 64138-49-4 N-(1-phenylethyl)pyridin-2-ylamine 
• 93725-14-5 N,N-dimethyl-N'-(1-phenyl-ethyl)-N'-[2]pyridyl-ethylenediamine 
• 96354-74-4 N-(diphenylmethyl)pyridin-2-amine 
• 74037-48-2 N-(1,2-diphenylethyl)pyridin-2-amine 
• 63232-84-8 N-(morpholin-4-yl-phenyl-methyl)-N-pyridin-2-yl-benzamide 
• 10254-52-1 2-phenyl-3-(pyridin-2-yl)-1,3-thiazolidin-4-one 
• 54214-70-9 2,3-diphenyl-4H-pyrido[1,2-a]pyrimidin-4-one 
• 59046-00-3 3-chloro-2-phenylpyrido<1,2-a>pyrimidin-4(4H)-one 
• 91538-37-3 3,3-dichloro-4-phenyl-1-(2-pyridyl)-2-azetidinone 
• 91538-38-4 methyl 2,2-dichloro-3-phenyl-3-(2-pyridylamino)propanoate 
• 159639-04-0 4,4-dimethyl-1-phenyl-1-(pyridin-2-yl)aminopropan-3-one 
• 91538-35-1 2,2-dichloro-3-phenyl-3-(2-pyridylamino)propanoic acid 
• 64413-91-8 2-phenyl-3-chloroimidazo<1,2-a>pyridine 
• 4044-95-5 2-Phenyl-3-bromoimidazo<1,2-a>pyridine 

Relevant articles and documents

Study of N-benzylidene derivatives synthesized as corrosion inhibitors for copper in HCl solution

Corrosion inhibition of the two N-benzylidene derivative compounds, namely N-benzylidene pyridin-2 amine (NBPA) and N-(4-choloromethylbenzylidene) pyridin-2 amine (NCMBPA) as corrosion inhibitors for copper in hydrochloric acid 6.0 M have been studied by

Ru(II)-NHC catalysed N-Alkylation of amines with alcohols under solvent-free conditions

The reaction of [RuCl2(p-cymene)]2 with in situ prepared Ag-N-heterocyclic carbene (NHC) complexes yields a series of [RuCl2(p-cymene)(NHC)] complexes (2). All of the complexes have been characterised by elemental analysis, and 1H NMR and 13C NMR spectroscopies. These complexes have been tested for the N-alkylation of aromatic amines with arylmethyl alcohols under neat conditions in the presence of KOtBu at 120 °C. Compounds (2) are stable and have high catalytic/selective activity for the N-alkylation reactions of primary amines to afford secondary amines.

Rh(III)-Catalyzed imidoyl C-H carbamylation and cyclization to bicyclic [1,3,5]triazinones

A Rh(III)-catalyzed synthesis of bicyclic [1,3,5]-triazinones from a diverse array of imines coupled with ethyl (pivaloyloxy)carbamate is reported. The preparation of [5,6]- and [6,6]-bicyclic heterocycles substituted with aryl, alkyl, and alkoxy groups demonstrated a broad reaction scope. The efficiency of this approach was further enhanced with the development of a three-component variant featuring in situ imine formation. X-ray crystallographic characterization of a rhodacycle formed by imidoyl C-H activation provides support for the proposed mechanism.