188837-55-0Relevant articles and documents
Aminolysis of aryl ester using tertiary amine as amino donor via c-o and c-n bond activations
Bao, Yong-Sheng,Zhaorigetu, Bao,Agula, Bao,Baiyin, Menghe,Jia, Meilin
, p. 803 - 808 (2014/04/03)
An aminolysis reaction between various aryl esters and inert tertiary amines by C-O and C-N bond activations has been developed for the selective synthesis of a broad scope of tertiary amides under neutral and mild conditions. The mechanism may undergo the two key steps of oxidative addition of acyl C-O bond in parent ester and C-N bond cleavage of tertiary amine via an iminium-type intermediate.
1,3,4-Oxadiazole formation as traceless release in solid phase organic synthesis
Cesarini, Sara,Colombo, Nicoletta,Pulici, Maurizio,Felder, Eduard R.,Brill, Wolfgang K.-D.
, p. 10223 - 10236 (2007/10/03)
Oxadiazoles were generated upon a dehydrative cyclization reaction with 2-acyl hydrazides bound to the polymeric support via one of their N atoms using TFAA as a dehydration agent.