18890-22-7

Basic information

• Product Name: 2-Cyclohexen-1-ol, 3-methyl-, (1R)-
• CAS NO: 18890-22-7
• Molecular Formula: C7H12O
• Molecular Weight: 112.172
• Mol File: 18890-22-7.mol
• Article Data: 22

Chemical Properties

• CAS DataBase Reference: 2-Cyclohexen-1-ol, 3-methyl-, (1R)-(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Cyclohexen-1-ol, 3-methyl-, (1R)-(18890-22-7)
• EPA Substance Registry System: 2-Cyclohexen-1-ol, 3-methyl-, (1R)-(18890-22-7)

Safety Data

• Hazardous Substances Data: 18890-22-7(Hazardous Substances Data)

Upstream product

• 1193-18-6 3-methylcyclohexen-2-one 
• 140710-03-8 2-Iodo-3-methyl-2-cyclohexen-1-one 
• 51326-00-2 2-bromo-3-ethoxycyclohex-2-en-1-one 
• 5323-87-5 3-Ethoxycyclohex-2-en-1-one 
• 108-22-5 Isopropenyl acetate 
• 21378-21-2 3-methylcyclohex-2-en-1-ol 
• 69744-93-0 Phthalic acid mono-((R)-3-iodo-cyclohex-2-enyl) ester 
• 56671-82-0 3-Iodocyclohex-2-enone 
• 51326-26-2 α-bromo-3-methylcyclohex-2-en-1-one 
• 1489-56-1 1-methyl-1,3-cyclohexadiene 
• 69744-95-2 (R)-(+)-iodocyclohex-2-en-1-ol 
• 917-54-4 methyllithium 
• 115073-43-3 (R)-3-methyl-2-cyclohexenyl acetate 
• 127000-15-1 (R)-(+)-2-bromo-3-methylcyclohex-2-en-1-ol 

Downstream Products

• 69698-86-8 (3S,8S,9S,10R,13S,14S,17S)-3-Acetoxy-10,13-dimethyl-2,3,4,7,8,9,10,11,12,13,14,15,16,17-tetradecahydro-1H-cyclopenta[a]phenanthrene-17-carboxylic acid (R)-3-methyl-cyclohex-2-enyl ester 
• 248916-33-8 (1R)-3-methyl-2-cyclohexenyl (3R)-4-benzyloxy-3-methylbutanoate 
• 152976-07-3 (2S,3S)-2,3-epoxy-3-methylcyclohexanone 
• 87680-39-5 (3S,6R,7S)-1,10-bisaboladien-3-ol 
• 72346-47-5 (3S,6R,7R)-1,10-bisaboladien-3-ol 

Relevant articles and documents

Enantioselective hydride transfer hydrogenation of ketones catalyzed by [(η6-p-cymene)Ru(amino acidato)Cl] and [(η6-p-cymene)Ru(amino acidato)]3(BF4)3 complexes

The new complexes (RRuSC, SRuSC)-[(η6-pCym)Ru(L-Aze)Cl] (6a, b), (RRuSC, SRuSC)-[(η6-pCym)Ru(L-Pip)Cl] (7a, b), (RRuRRuRRuSCSCSCSNSNSN, SRuSRuSRuSCSCSCSNSNSN)-[{(η6-pCym)Ru(L-Aze)}3](BF4)3 (8a, b) and (RRuRRuRRuSCSCSCSNSNSN, SRuSRuSRuSCSCSCSNSNSN)-[{(η6-pCym)Ru(L-Pip)}3](BF4)3 (9a, b) (L-Aze=L-2-azetidinecarboxylate, L-Pip=L-2-piperidinecarboxylate) were prepared, characterized and used, together with the known [{(η6-pCym)Ru(L-Pro)}3](BF4)3, 5 and [{(η6-pCym)Ru(L-Ala)}3](BF4)3, 10 (L-Pro=L-prolinate, L-Ala=L-alaninate), in hydride transfer reduction of acetophenone, a series of substituted acetophenones and several other ketones with moderate to high conversions and enantioselectivities up to 86% e.e.

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