19190-61-5Relevant articles and documents
Synthesis of perfluorinated vinyl ethers having ester group
Yamabe, Masaaki,Munekata, Seiji,Kaneko, Isamu,Ukihashi, Hiroshi
, p. 65 - 68 (1999)
A new efficient and convenient synthetic process of perfluorinated vinyl ethers containing an ester group was developed by pyrolysis in the presence of α-trifluoromethyl moiety without loss of -COF functional group followed by alcoholysis in high yield.
Method for producing fluorinated compound
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Paragraph 0433; 0438; 0439, (2016/12/22)
Provided is a method for producing a desired perfluorinated product with high yield by a fluorination reaction of a partially fluorinated ester. A compound (3), which is produced by reacting a compound (1) with a compound (2) (and which has a fluorine content of 30 mass% or more), is fluorinated in a liquid phase to produce a perfluorinated compound (4), wherein the compound (1) is represented by the formula HOCH2-RA-CH2OH and the compound (2) is represented by the formula X1C(=O)-C(RB)(RC)(RD). RA represents a bivalent saturated hydrocarbon group or the like and does not have a hetero atom such as an ethereal oxygen atom. X1 represents a halogen atom, and -C(RB)(RC)(RD) represents a branched group.
Polyfluorinated ethers: IV.* By-products in the synthesis of polyfluorinated alkyl vinyl ethers in a solvating solvent
Yuminov
, p. 1715 - 1720 (2007/10/03)
By-products formed in the synthesis of perfluoro(propyl vinyl ether), perfluoro(2-propoxypropyl vinyl ether), and methyl perfluoro(4-vinyloxybutanoate) in a solvating solvent have been studied. 1998 MAHK "Hayka/Interperiodica".