1925-54-8

Basic information

• Product Name: 1-(bromomethyl)-7,7-dimethylbicyclo[2.2.1]heptan-2-one
• Synonyms: 1-(Bromomethyl)-7,7-dimethylbicyclo(2.2.1)heptan-2-one; 1-(Bromomethyl)-7,7-dimethylbicyclo[2.2.1]heptan-2-one; 217-656-0
• CAS NO: 1925-54-8
• Molecular Formula: C₁₀H₁₅BrO
• Molecular Weight: 231.14
• EINECS: 217-656-0
• Mol File: 1925-54-8.mol
• Article Data: 2

Chemical Properties

• Boiling Point: 269.4°Cat760mmHg
• Flash Point: 52.7°C
• Appearance: /
• Density: 1.366g/cm³
• Vapor Pressure: 0.00725mmHg at 25°C
• Refractive Index: 1.528
• CAS DataBase Reference: 1-(bromomethyl)-7,7-dimethylbicyclo[2.2.1]heptan-2-one(CAS DataBase Reference)
• NIST Chemistry Reference: 1-(bromomethyl)-7,7-dimethylbicyclo[2.2.1]heptan-2-one(1925-54-8)
• EPA Substance Registry System: 1-(bromomethyl)-7,7-dimethylbicyclo[2.2.1]heptan-2-one(1925-54-8)

Safety Data

• Hazardous Substances Data: 1925-54-8(Hazardous Substances Data)

Usage

General Description

1-(bromomethyl)-7,7-dimethylbicyclo[2.2.1]heptan-2-one is a chemical compound with the molecular formula C10H17BrO. It is a bicyclic ketone with a bromomethyl group attached to one of its carbon atoms. 1-(bromomethyl)-7,7-dimethylbicyclo[2.2.1]heptan-2-one is commonly used as an intermediate in organic synthesis, particularly in the production of pharmaceuticals and agrochemicals. It is also used as a building block for the synthesis of various compounds with biological activity. 1-(bromomethyl)-7,7-dimethylbicyclo[2.2.1]heptan-2-one has potential applications in the development of new drugs and in the production of fine chemicals.

InChI:InChI=1/C10H15BrO/c1-9(2)7-3-4-10(9,6-11)8(12)5-7/h7H,3-6H2,1-2H3

Upstream product

• 79-92-5 camphene 
• 76-26-6 camphor-10-sulfonic acid 
• 51361-76-3 (+)(1R)-10-bromo-bornanol-(2ξ) 
• 464-49-3 (1R,4R)-1,7,7-trimethylbicyclo[2.2.1]heptan-2-one 
• 5872-08-2 10-camphorsufonic acid 
• 21791-95-7 Potassium; ((1S,4R)-7,7-dimethyl-2-oxo-bicyclo[2.2.1]hept-1-yl)-methanesulfonate 

Downstream Products

• 25435-53-4 (2,2,3-Trimethyl-cyclopent-3-enyl)-acetic acid 
• 76-22-2 Camphor 
• 93727-18-5 trans-10-Benzyliden_.campher 

Relevant articles and documents

Synthesis and photooxidation of styrene copolymer bearing camphorquinone pendant groups

Abstract (±)-10-Methacryloyloxycamphorquinone (MCQ) was synthesized from (±)-10-camphorsulfonic acid either by a known seven-step synthetic route or by a novel, shorter five-step synthetic route. MCQ was copolymerized with styrene (S) and the photochemical behavior of the copolymer MCQ/S was compared with that of a formerly studied copolymer of styrene with monomers containing the benzil (BZ) moiety (another 1,2-dicarbonyl). Irradiation (λ > 380 nm) of aerated films of styrene copolymers with monomers containing the BZ moiety leads to the insertion of two oxygen atoms between the carbonyl groups of BZ and to the formation of benzoyl peroxide (BP) as pendant groups on the polymer backbone. An equivalent irradiation of MCQ/S led mainly to the insertion of only one oxygen atom between the carbonyl groups of camphorquinone (CQ) and to the formation of camphoric anhydride (11) covalently bound to the polymer backbone. While the decomposition of pendant BP groups formed in irradiated films of styrene copolymers with pendant BZ groups leads to crosslinking, only small molecular-weight changes in irradiated MCQ/S were observed.