194302-50-6

Basic information

• Product Name: ((S)-2-((S)-4-Benzyl-2-oxo-oxazolidin-3-yl)-1-{(1R,2R)-2-[(S)-2-((S)-4-benzyl-2-oxo-oxazolidin-3-yl)-1-tert-butoxycarbonylamino-2-oxo-ethyl]-cyclopropyl}-2-oxo-ethyl)-carbamic acid tert-butyl ester
• CAS NO: 194302-50-6
• Molecular Weight: 706.793
• Mol File: 194302-50-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: ((S)-2-((S)-4-Benzyl-2-oxo-oxazolidin-3-yl)-1-{(1R,2R)-2-[(S)-2-((S)-4-benzyl-2-oxo-oxazolidin-3-yl)-1-tert-butoxycarbonylamino-2-oxo-ethyl]-cyclopropyl}-2-oxo-ethyl)-carbamic acid tert-butyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: ((S)-2-((S)-4-Benzyl-2-oxo-oxazolidin-3-yl)-1-{(1R,2R)-2-[(S)-2-((S)-4-benzyl-2-oxo-oxazolidin-3-yl)-1-tert-butoxycarbonylamino-2-oxo-ethyl]-cyclopropyl}-2-oxo-ethyl)-carbamic acid tert-butyl ester(194302-50-6)
• EPA Substance Registry System: ((S)-2-((S)-4-Benzyl-2-oxo-oxazolidin-3-yl)-1-{(1R,2R)-2-[(S)-2-((S)-4-benzyl-2-oxo-oxazolidin-3-yl)-1-tert-butoxycarbonylamino-2-oxo-ethyl]-cyclopropyl}-2-oxo-ethyl)-carbamic acid tert-butyl ester(194302-50-6)

Safety Data

• Hazardous Substances Data: 194302-50-6(Hazardous Substances Data)

Upstream product

• 24424-99-5 di-tert-butyl dicarbonate 
• 194302-47-1 (1R,2R)-1,2-bis[(1S)-azido-2-oxo-2((4S)-benzyl-2-oxo-3-oxazolidinyl)ethyl]cyclopropane 
• 82442-59-9 ((1S*,2S*)-cyclopropane-1,2-diyl)dimethanol 
• 54010-19-4 trans-Cyclopropyl-diessigsaeure-(1,2) 
• 702-28-3 1,2-cyclopropane dicarboxylic acid diester 
• 89693-69-6 ((1S,2S)-2-Cyanomethyl-cyclopropyl)-acetonitrile 

Relevant articles and documents

Stereoselective synthesis of cyclopropane-1,2-bis(glycine) derivatives

Conformationally constrained bis(glycines) as trans derivatives of cyclopropane have been prepared in stereoselective syntheses. (S)-4-Benzyl-2-oxazolidinone was used as a chiral auxiliary, trisyl azide was the electrophilic source of amine nitrogen. Four stereogenic centers were created. A related cis-cyclopropane derivative suffered ring closure with formation of a bicyclo[3.1.0]hex-3-one derivative. X-ray data for the latter and for (1S,2S)-1,2-bis{(1S)-azido-2-oxo-2[(4S)-benzyl-2-oxo-3-oxazolidinyl] -ethyl}cyclopropane are presented.