702-28-3

Basic information

• Product Name: Cyclopropane-1,2-dicarboxylic acid dimethyl ester
• Synonyms: Cyclopropane-1,2-dicarboxylic acid dimethyl ester;Dimethyl 1,2-cyclopropanedicarboxylate;Dimethyl cyclopropane-1,2-dicarboxylate
• CAS NO: 702-28-3
• Molecular Formula: C₇H₁₀O₄
• Molecular Weight: 158.1519
• Mol File: 702-28-3.mol
• Article Data: 5

Chemical Properties

• Boiling Point: 219°C (estimate)
• Appearance: /
• Density: 1.1584
• Refractive Index: 1.4472 (estimate)
• Storage Temp.: 2-8°C
• CAS DataBase Reference: Cyclopropane-1,2-dicarboxylic acid dimethyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Cyclopropane-1,2-dicarboxylic acid dimethyl ester(702-28-3)
• EPA Substance Registry System: Cyclopropane-1,2-dicarboxylic acid dimethyl ester(702-28-3)

Safety Data

• Hazardous Substances Data: 702-28-3(Hazardous Substances Data)

Usage

Synthesis Reference(s)

The Journal of Organic Chemistry, 48, p. 1125, 1983 DOI: 10.1021/jo00155a047

Upstream product

• 1119-40-0 Dimethyl glutarate 
• 96-34-4 methyl chloroacetate 
• 292638-85-8 acrylic acid methyl ester 
• 89363-76-8 C₁₇H₁₉O₄S⁽¹⁺⁾*BF₄^(1-) 

Downstream Products

• 1489-58-3 trans-1,2-cyclopropanedicarboxylic acid 
• 194302-48-2 (1S,2S)-1,2-bis[(1S)-azido-2-oxo-2((4S)-benzyl-2-oxo-3-oxazolidinyl)ethyl]cyclopropane 
• 194302-47-1 (1R,2R)-1,2-bis[(1S)-azido-2-oxo-2((4S)-benzyl-2-oxo-3-oxazolidinyl)ethyl]cyclopropane 
• 194302-52-8 ((S)-2-((S)-4-Benzyl-2-oxo-oxazolidin-3-yl)-1-{(1S,2S)-2-[(S)-2-((S)-4-benzyl-2-oxo-oxazolidin-3-yl)-1-tert-butoxycarbonylamino-2-oxo-ethyl]-cyclopropyl}-2-oxo-ethyl)-carbamic acid tert-butyl ester 
• 194302-50-6 ((S)-2-((S)-4-Benzyl-2-oxo-oxazolidin-3-yl)-1-{(1R,2R)-2-[(S)-2-((S)-4-benzyl-2-oxo-oxazolidin-3-yl)-1-tert-butoxycarbonylamino-2-oxo-ethyl]-cyclopropyl}-2-oxo-ethyl)-carbamic acid tert-butyl ester 
• 194302-64-2 (1R,2S)-1,2-bis[2-oxo-2-((4S)-benzyl-2-oxo-3-oxazolidinyl)ethyl]cyclopropane 
• 5617-74-3 cis-1,2-cyclopropanedicarboxylic acid anhydride 
• 111887-64-0 (1aR,1bS,3R,5aS)-3-Phenyl-hexahydro-4-oxa-4a-aza-cyclopropa[a]pentalene 
• 111887-64-0 (1aR,1bS,3S,5aS)-3-Phenyl-hexahydro-4-oxa-4a-aza-cyclopropa[a]pentalene 
• 13279-88-4 (1RS,2RS)-1,2-cyclopropanedicarboxylic acid monomethyl ester 

Relevant articles and documents

Secondary Deuterium Kinetic Isotope Effects at the Termini of cis-1,2-Divinylcyclopropane and cis-1,2-Divinylcyclobutane in Their 3,3-Sigmatropic Shifts: Evidence for Different Transition-State Structures

In an effort to understand the substantially lower activation energy for the 3,3-sigmatropic shift of cis-1,2-divinylcyclopropane relative to that of cis-1,2-divinylcyclobutane, we determined the secondary deuterium kinetic isotope effects (KIEs) at the vinyl termini of both materials.For the cyclopropane derivative, kH/kd4 = 1/1.29 (+/- 0.09) at 10 deg C in deuteriochloroform.For the cyclobutane derivative, kH/kd4 = 1/1.04 (+/- 0.02) at 77.7 deg C in hexachlorobutadiene solvent.These KIEs indicate that there is much more bonding at the terminal carbons in the transition state for the rearrangement of the cyclopropane analogue and relatively little bonding at the termini in the rearrangement of the cyclobutane material.

Arylation of Dialkyl Sulfides and of Aryl Alkyl Sulfides To Provide Sulfonium Salts

-

Cis-N,N,N',N'-tetramethylcyclopropane-1,2-dicarboxamide and use thereof

cis-N,N,N',N'-Tetramethylcyclopropane-1,2-dicarboxamide as a new chemical compound, and the use thereof in the regulation of plant growth.