19620-36-1

Basic information

• Product Name: Cyclohexanone, 4-(1-methylethylidene)-
• CAS NO: 19620-36-1
• Molecular Formula: C9H14O
• Molecular Weight: 138.21
• Mol File: 19620-36-1.mol
• Article Data: 7

Chemical Properties

• CAS DataBase Reference: Cyclohexanone, 4-(1-methylethylidene)-(CAS DataBase Reference)
• NIST Chemistry Reference: Cyclohexanone, 4-(1-methylethylidene)-(19620-36-1)
• EPA Substance Registry System: Cyclohexanone, 4-(1-methylethylidene)-(19620-36-1)

Safety Data

• Hazardous Substances Data: 19620-36-1(Hazardous Substances Data)

Upstream product

• 24903-95-5 nopinone 
• 113580-94-2 4-chloro-4-(1'-methylethyl)cyclohexan-1-one 
• 121-69-7 N,N-dimethyl-aniline 
• 19620-35-0 8-(propan-2-ylidene)-1,4-dioxaspiro[4.5]decane 
• 4379-08-2 3-isopropenyl-pentane-1,3,5-tricarboxylic acid 
• 7664-93-9 sulfuric acid 
• 861575-49-7 8-bromo-6-oxo-m-menthan-7-oic acid ethyl ester 
• 861575-76-0 6-oxo-m-menth-3⁽⁸⁾-en-7-oic acid ethyl ester 
• 4746-97-8 cyclohexanedione monoethylene ketal 

Downstream Products

• 175020-74-3 4-isopropylidene-cyclohexanol 
• 913748-00-2 4-(propan-2-ylidene)cyclohexan-1-one oxime 
• 35931-84-1 4-isopropylidene-cyclohex-1-ene carbaldehyde 
• 1383381-41-6 4-(bis-N,N’-4-isopropylidene cyclohex-1-enylmethyloxycarbonyl[5-(2,5-dimethylphenyl)-3-trifluoromethylpyrazol-1-yl]benzenesulfonamide) 
• 1383381-40-5 4-(3-(cyclopentyloxy-4-methoxyphenyl)-2-oxo-pyrrolidine-1-carboxylic acid 4-isopropylidenecyclohex-1-enylmethyl ester) 
• 1383381-39-2 isoperillyl chloroformate 
• 1383381-38-1 (3-methyl 4-oxo-3,4-dihydroimidazo[5,1-d][1,2,3,5]tetrazine-8-carbonyl)-carbamic acid-4-isopropylidene cyclohex-1-enylmethyl ester 

Relevant articles and documents

Domino Aryne Annulation via a Nucleophilic-Ene Process

1,2-Benzdiyne equivalents possess the unique property that they can react with two arynophiles through iteratively generated 1,2- and 2,3-aryne intermediates. Upon rational modification on the second leaving group of these aryne precursors, a domino aryne annulation approach was developed through a nucleophilic-ene reaction sequence. Various benzo-fused N-heterocyclic frameworks were achievable under transition metal-free conditions with a broad substrate scope.

METHODS AND DEVICES FOR USING ISOPERILLYL ALCOHOL

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Enantioselective synthesis of (+)-α-vetivone through the Michael reaction of chiral imines

(+)-α-Vetivone has been synthesised in nine steps. The absolute stereochemistry of the two stereogenic centres is controlled in the same key step involving the stereoselective Michael addition of a chiral imine of 4-isopropylidene-2-methylcyclohexanone to phenyl crotonate.