19647-26-8

Basic information

• Product Name: Benzene, [(1Z)-2-bromo-1-methylethenyl]-
• CAS NO: 19647-26-8
• Molecular Formula: C9H9Br
• Molecular Weight: 197.074
• Mol File: 19647-26-8.mol
• Article Data: 33

Chemical Properties

• CAS DataBase Reference: Benzene, [(1Z)-2-bromo-1-methylethenyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, [(1Z)-2-bromo-1-methylethenyl]-(19647-26-8)
• EPA Substance Registry System: Benzene, [(1Z)-2-bromo-1-methylethenyl]-(19647-26-8)

Safety Data

• Hazardous Substances Data: 19647-26-8(Hazardous Substances Data)

Upstream product

• 31778-29-7 1-bromo-2-phenylpropan-2-ol 
• 704-79-0 3-phenylbut-2-enoic acid 
• 3112-88-7 Benzyl phenyl sulfone 
• 704-80-3 (E)-3-phenyl-2-butenoic acid 
• 3360-53-0 1-bromo-2-phenyl-1-propene 
• 98-82-8 Isopropylbenzene 
• 66775-59-5 PhMeC=CHAlMe₂ 
• 98-86-2 acetophenone 
• 2065-66-9 methyl-triphenylphosphonium iodide 
• 99-90-1 para-bromoacetophenone 
• 123848-50-0 1,1-dibromo-2-phenylpropan-2-ol 
• 100-44-7 benzyl chloride 
• 98-83-9 isopropenylbenzene 
• 16917-35-4 (E)-(1-bromoprop-1-en-2-yl)benzene 

Downstream Products

• 673-32-5 1-Phenylprop-1-yne 
• 637-50-3 1-phenylpropene 
• 54624-37-2 (E)-(2-bromoprop-1-en-1-yl)benzene 
• 21453-89-4 (Z)-(2-bromoprop-1-en-1-yl)benzene 
• 2327-99-3 1-phenylpropadiene 
• 16917-35-4 (E)-(1-bromoprop-1-en-2-yl)benzene 
• 98-86-2 acetophenone 
• 98-83-9 isopropenylbenzene 
• 372193-54-9 (2-(prop-1-en-2-yl)phenyl)boronic acid 
• 1429762-91-3 C₂₁H₁₉OP 
• 16819-47-9 2,5-diphenylhexa-2,4-diene 
• 833-81-8 1,2-diphenylpropene 
• 74866-37-8 [3-(benzenesulfonyl)prop-1-en-2-yl]benzene 
• 61370-30-7 2-phenyl-3,3-(2,2'-biphenyldiyl)-2-propene 

Relevant articles and documents

Visible light photocatalytic one pot synthesis of: Z -arylvinyl halides from e -arylvinyl acids with N -halosuccinimide

An efficient visible light photocatalytic strategy to synthesize thermodynamically less stable Z-arylvinyl halides (with up to >99/1 Z/E ratio and 86% yield) was developed. The reaction combined base-mediated halodecarboxylation of E-arylvinyl acids with N-halosuccinimide and visible light Ir-photocatalyzed isomerization of E-arylvinyl halides in a one pot sequential catalytic process. This journal is

Photocatalytic Isomerization of Styrenyl Halides: Stereodivergent Synthesis of Functionalized Alkenes

An efficient and general method for the isomerization of styrenyl halides under different photocatalytic conditions (fac-Ir(ppy)3 in methanol for E to Z isomerization and fluorescein in 1,4-dioxane for Z to E isomerization, respectively) is disclosed. A series of stereospecific transformations constitute preliminary validation of this strategy in the synthesis of functionalized alkenes, including two diaryl alkenes, a styrenyl boronic ester and an enyne. The photocatalytic isomerization and subsequent cross coupling reaction can be run in a one-pot manner. The stereodivergent synthesis of all four isomers of a conjugated diene, as well as the antitumor agent DMU-212 and its (Z)-isomer highlights the synthetic applicability of this method.

Nickel-Catalyzed Reductive Cross-Coupling of Vinyl Bromides with Unactivated Alkyl Halides

The use of pyridine as the sole ligand for the reductive vinylation of unactivated secondary alkyl halides under Ni-catalyzed conditions has been developed. Both alkyl- and aryl-substituted vinyl bromides are suitable, in which alkyl-decorated α-alkenyl bromides resulted in the α-products in good results.