19672-25-4

Basic information

• Product Name: diethyl ester of hydroazobenzene-4,4'-dicarboxylic acid
• Synonyms: diethyl ester of hydroazobenzene-4,4'-dicarboxylic acid
• CAS NO: 19672-25-4
• Molecular Weight: 328.368
• Mol File: 19672-25-4.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: diethyl ester of hydroazobenzene-4,4'-dicarboxylic acid(CAS DataBase Reference)
• NIST Chemistry Reference: diethyl ester of hydroazobenzene-4,4'-dicarboxylic acid(19672-25-4)
• EPA Substance Registry System: diethyl ester of hydroazobenzene-4,4'-dicarboxylic acid(19672-25-4)

Safety Data

• Hazardous Substances Data: 19672-25-4(Hazardous Substances Data)

Upstream product

• 99-77-4 ethyl 4-nitrobenzoate 
• 73183-34-3 bis(pinacol)diborane 
• 7250-68-2 4,4'-bis(ethoxycarbonyl)azobenzene 
• 7250-68-2 (E)-diethyl 4,4′-(diazene-1,2-diyl)dibenzoate 
• 62-23-7 4-nitro-benzoic acid 
• 10252-29-6 azobenzene-4,4'-dicarbonyl dichloride 
• 586-91-4 azobenzene-4,4'-dicarboxylic acid 
• 7476-79-1 4-nitrosobenzoic acid ethyl ester 
• 6421-04-1 4,4'-azoxy-di-benzoic acid diethyl ester 
• 94-09-7 p-aminoethylbenzoate 

Downstream Products

• 7250-68-2 (E)-diethyl 4,4′-(diazene-1,2-diyl)dibenzoate 
• 102003-40-7 4,4'-(4-isopropyl-3,5-dioxo-pyrazolidine-1,2-diyl)-di-benzoic acid 
• 101869-48-1 4,4'-(4-ethyl-3,5-dioxo-pyrazolidine-1,2-diyl)-di-benzoic acid 
• 94-09-7 p-aminoethylbenzoate 
• 7250-68-2 4,4'-bis(ethoxycarbonyl)azobenzene 
• 102955-97-5 4,4'-(4-isopropyl-3,5-dioxo-pyrazolidine-1,2-diyl)-di-benzoic acid diethyl ester 
• 38022-19-4 4,4'-(4-butyl-3,5-dioxo-pyrazolidine-1,2-diyl)-bis-benzoic acid diethyl ester 
• 103157-58-0 4,4'-(4-hexyl-3,5-dioxo-pyrazolidine-1,2-diyl)-di-benzoic acid diethyl ester 
• 114400-14-5 4,4'-(3,5-dioxo-4-propyl-pyrazolidine-1,2-diyl)-di-benzoic acid diethyl ester 
• 38022-20-7 4,4'-(4-ethyl-3,5-dioxo-pyrazolidin-1,2-diyl)-bis-benzoic acid diethyl ester 

Relevant articles and documents

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Chemoselective electrochemical reduction of nitroarenes with gaseous ammonia

Valuable aromatic nitrogen compounds can be synthesized by reduction of nitroarenes. Herein, we report electrochemical reduction of nitroarenes by a protocol that uses inert graphite felt as electrodes and ammonia as a reductant. Depending on the cell voltage and the solvent, the protocol can be used to obtain aromatic azoxy, azo, and hydrazo compounds, as well as aniline derivatives with high chemoselectivities. The protocol can be readily scaled up to >10 g with no decrease in yield, demonstrating its potential synthetic utility. A stepwise cathodic reduction pathway was proposed to account for the generations of products in turn.

Activation method of bis(pinacolato)diborane and application thereof

The invention discloses an activation method of bis(pinacolato)diborane. R substituted pyridine induces the homolysis of bis(pinacolato)diborane to obtain boron free radicals, and the process is shown by a formula I, wherein R refers to independent cyano and nitro. The invention also provides an application of the activation method of bis(pinacolato)diborane. Specifically, the activation method is applied to the synthesis of hydro-azobenzene derivatives.