19889-37-3Relevant articles and documents
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Roland et al.
, p. 2122 (1950)
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Metal complex containing three different ligands
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Paragraph 0142; 0146-0148, (2020/11/22)
A metal complex containing three different ligands is disclosed. The metal complex contains three different ligands, and can be used as a luminescent material in a luminescent layer of an organic electroluminescent device. The novel complexes not only can achieve the device performance expected to be regulated or improved by regulating substituent groups, but also can achieve the effect of effectively controlling the rise of the evaporation temperature. An electroluminescent device and a compound formulation comprising the metal complex are also disclosed.
Palladium-Catalyzed C(sp3)-H Oxygenation via Electrochemical Oxidation
Yang, Qi-Liang,Li, Yi-Qian,Ma, Cong,Fang, Ping,Zhang, Xiu-Jie,Mei, Tian-Sheng
supporting information, p. 3293 - 3298 (2017/03/11)
Palladium-catalyzed C-H activation/C-O bond-forming reactions have emerged as attractive tools for organic synthesis. Typically, these reactions require strong chemical oxidants, which convert organopalladium(II) intermediates into the PdIII or PdIV oxidation state to promote otherwise challenging C-O reductive elimination. However, previously reported oxidants possess significant disadvantages, including poor atom economy, high cost, and the formation of undesired byproducts. To overcome these issues, we report an electrochemical strategy that takes advantage of anodic oxidation of PdII to induce selective C-O reductive elimination with a variety of oxyanion coupling partners.