198978-09-5

Basic information

• Product Name: 1-(1,3-dimethyl-2-cyclohexenyl)-3-buten-2-one
• Synonyms: 1-(1,3-dimethyl-2-cyclohexenyl)-3-buten-2-one
• CAS NO: 198978-09-5
• Molecular Weight: 178.274
• Mol File: 198978-09-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1-(1,3-dimethyl-2-cyclohexenyl)-3-buten-2-one(CAS DataBase Reference)
• NIST Chemistry Reference: 1-(1,3-dimethyl-2-cyclohexenyl)-3-buten-2-one(198978-09-5)
• EPA Substance Registry System: 1-(1,3-dimethyl-2-cyclohexenyl)-3-buten-2-one(198978-09-5)

Safety Data

• Hazardous Substances Data: 198978-09-5(Hazardous Substances Data)

Upstream product

• 1193-18-6 3-methylcyclohexen-2-one 
• 38053-91-7 2-trimethylsilyloxy-1,3-butadiene 
• 29481-98-9 1,3-dimethyl-2-cyclohexen-1-ol 

Downstream Products

• 198978-11-9 1-(1,3-dimethyl-2-cyclohexenyl)-4-nitro-2-butanone ethylene acetal 
• 198978-10-8 1-(1,3-dimethyl-2-cyclohexenyl)-4-nitro-2-butanone 

Relevant articles and documents

Oxidative Generation of 1-Nitroalkyl Radicals and Their Addition Reaction to Olefins

1-Nitroalkyl radicals are generated by oxidation of potassium salt of 1-aci-nitroalkanes with ammonium hexanitratocerate(IV). When the oxidation is carried out in the presence of electron-rich olefins, such as silyl enol ethers, intermolecular addition of the radicals onto the olefins proceeds to afford β-nitro ketones, which are further converted to α,β-unsaturated ketones in high yield. Stereoselective construction of fused ring systems is achieved by intramolecular addition of 1-nitroalkyl radicals.