29481-98-9

Basic information

• Product Name: 2-Cyclohexen-1-ol, 1,3-dimethyl-
• CAS NO: 29481-98-9
• Molecular Formula: C8H14O
• Molecular Weight: 126.199
• Mol File: 29481-98-9.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: 2-Cyclohexen-1-ol, 1,3-dimethyl-(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Cyclohexen-1-ol, 1,3-dimethyl-(29481-98-9)
• EPA Substance Registry System: 2-Cyclohexen-1-ol, 1,3-dimethyl-(29481-98-9)

Safety Data

• Hazardous Substances Data: 29481-98-9(Hazardous Substances Data)

Upstream product

• 917-64-6 methyl magnesium iodide 
• 1193-18-6 3-methylcyclohexen-2-one 
• 60-29-7 diethyl ether 
• 75-16-1 methylmagnesium bromide 
• 917-54-4 methyllithium 

Downstream Products

• 37709-70-9 (1,3-Dimethyl-cyclohex-2-enyl)-acetic acid 
• 37709-71-0 1,3-Dimethyl-3-acetonyl-cyclohexen 
• 24720-09-0 α-damascone 
• 31191-93-2 2-methylene-6,6-dimethyl-1-[but-2-enoyl]-cyclohexane 
• 128749-93-9 1r.3c-dimethyl-cyclohexanediol-(1.3t) 
• 198978-11-9 1-(1,3-dimethyl-2-cyclohexenyl)-4-nitro-2-butanone ethylene acetal 
• 198978-10-8 1-(1,3-dimethyl-2-cyclohexenyl)-4-nitro-2-butanone 
• 198978-09-5 1-(1,3-dimethyl-2-cyclohexenyl)-3-buten-2-one 
• 15466-94-1 cis-1,3-Dimethylcyclohexan-1-ol 
• 23611-15-6 1-methylene-3-methyl-2-cyclohexene 
• 4573-05-1 1,3-dimethyl-1,3-cyclohexadiene 
• 503-47-9 1,3,3-trimethyl-1-cyclohexene 
• 611-01-8 2,4-dimethyl-benzoic acid 
• 37709-69-6 (1,3-Dimethyl-cyclohex-2-enyl)-acetic acid ethyl ester 

Relevant articles and documents

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Oxidative Generation of 1-Nitroalkyl Radicals and Their Addition Reaction to Olefins

1-Nitroalkyl radicals are generated by oxidation of potassium salt of 1-aci-nitroalkanes with ammonium hexanitratocerate(IV). When the oxidation is carried out in the presence of electron-rich olefins, such as silyl enol ethers, intermolecular addition of the radicals onto the olefins proceeds to afford β-nitro ketones, which are further converted to α,β-unsaturated ketones in high yield. Stereoselective construction of fused ring systems is achieved by intramolecular addition of 1-nitroalkyl radicals.

Regioselective Synthesis of Substituted Bicyclooct-3-ene-2,8-diones via Double Carbonylation of 1,3-Cyclohexadienes

Double carbonylation of 1,3-cyclohexadienes 1 is applied to the synthesis of substituted bicyclooct-3-ene-2,8-diones 4.The Lewis acid mediated ring enlargement of substituted cyclohexadiene complexes 2 produces the cycloheptanone alkyl allyl complexes 3 with high regioselectivity.Substituted bicyclic diketones 4 are obtained in high yields by treating the complexes 3 with carbon monoxide under pressure or by oxidative decomposition.The two carbonylation steps can also be performed in a one-pot version.