31191-93-2

Basic information

• Product Name: 2-Buten-1-one, 1-(2,2-dimethyl-6-methylenecyclohexyl)-, (E)-
• Synonyms: (E)-1-(2,2-Dimethyl-6-methylene-cyclohexyl)-but-2-en-1-one;γ-damascone trans;damascone gamma;γ-damascone;6,6-Dimethyl-2-methylen-1-trans-crotonyl-cyclohexan;trans-6,6-Dimethyl-2-methylen-1-crotonoyl-cyclohexan;6,6-dimethyl-2-methylene-1-crotonoylcyclohexane
• CAS NO: 31191-93-2
• Molecular Formula: C13H20O
• Molecular Weight: 192.301
• Mol File: 31191-93-2.mol
• Article Data: 9

Chemical Properties

• CAS DataBase Reference: 2-Buten-1-one, 1-(2,2-dimethyl-6-methylenecyclohexyl)-, (E)-(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Buten-1-one, 1-(2,2-dimethyl-6-methylenecyclohexyl)-, (E)-(31191-93-2)
• EPA Substance Registry System: 2-Buten-1-one, 1-(2,2-dimethyl-6-methylenecyclohexyl)-, (E)-(31191-93-2)

Safety Data

• Hazardous Substances Data: 31191-93-2(Hazardous Substances Data)

Upstream product

• 35076-50-7 γ-damascol 
• 67-56-1 methanol 
• 109988-97-8 6,6-dimethyl-2-methylene-(1(Z)-methylthio-1,3-butadiene)-1-yl cyclohexane 
• 35071-26-2 1-bromomethyl-3,3-dimethyl-1-cyclohexene 
• 83699-30-3 2-Dimethylamino-pent-4-enenitrile 
• 109988-98-9 methoxy-3 (dimethyl-6,6 methylene-2 cyclohexane)yl-1 butanone-1 
• 73956-65-7 1-(2'-2'-dimethyl-6'-methylidenecyclohexyl)-3-buten-1-one 
• 122203-48-9 4-(2',2'-dimethyl-6'-methylidenecyclohexyl)-1,6-heptadien-4-ol 
• 54200-63-4 2-acetyl-3,3-dimethylcyclohexanone 
• 39900-07-7 2-methylene-6,6-dimethyl-1-[3-amino-butanoyl]-cyclohexane 
• 144-55-8 sodium hydrogencarbonate 
• 54201-07-9 1-(2-hydroxy-2,6,6-trimethyl-cyclohexyl)-ethanone 
• 109988-96-7 methyl-γ-dithiocyclogeranate 
• 503-47-9 1,3,3-trimethyl-1-cyclohexene 

Downstream Products

• 24720-09-0 α-damascone 

Relevant articles and documents

New preparation methods for α-damascone, γ-damascone, and β-damascenone using pyronenes

γ- and δ-Pyronenes are terpenic synthons easily available from myrcene. They are used as intermediates in the synthesis of α-damascone, γ-damascones, and β-damascenone. Copyright Taylor & Francis Group, LLC.

β-Cleavage of Bis(homoallylic) Potassium Alkoxides. Synthesis of γ-Damascone

Starting from the γ-lactone cis-1, two new syntheses of γ-damascone ((E)-4) are described.In both syntheses, the key step involves the β-cleavage of a bis(homoallylic)potassium alkoxide, viz. the transformation of 3a to 20 and (E/Z)-4, and the conversion

Utilisation du N,N-dimethylaminol-acetonitrile pour la synthese regioselective de diallylcetones masquees. Application a la synthese de la γ-damascone

A general synthetic approach to diallyl-ketones protected as α-amino-nitriles is reported.Starting from dimethylamino-acetonitrile, the sequential dialkylation with various allylic halides is conveniently performed at room temperature by using potassium c