109988-97-8Relevant articles and documents
NOUVELLE APPLICATION DE LA REACTION DES ORGANOMAGNESIENS SUR LES DITHIOESTERS : SYNTHESE DE LA GAMMA-DAMASCONE
Gosselin, Pascal
, p. 5495 - 5496 (1986)
A new synthetic route to γ-damascone 1 starting from methyl-γ-dithiocyclogeranate 2 is described.Addition of HMPT is found necessary to perform the reaction of allylmagnesium bromide with dithioester 2.A new, mild hydrolysis method is developped in order to transform the resulting vinylsulfide 4 into 1.