109988-98-9

Basic information

• Product Name: methoxy-3 (dimethyl-6,6 methylene-2 cyclohexane)yl-1 butanone-1
• CAS NO: 109988-98-9
• Molecular Weight: 224.343
• Mol File: 109988-98-9.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: methoxy-3 (dimethyl-6,6 methylene-2 cyclohexane)yl-1 butanone-1(CAS DataBase Reference)
• NIST Chemistry Reference: methoxy-3 (dimethyl-6,6 methylene-2 cyclohexane)yl-1 butanone-1(109988-98-9)
• EPA Substance Registry System: methoxy-3 (dimethyl-6,6 methylene-2 cyclohexane)yl-1 butanone-1(109988-98-9)

Safety Data

• Hazardous Substances Data: 109988-98-9(Hazardous Substances Data)

Upstream product

• 109988-96-7 methyl-γ-dithiocyclogeranate 
• 109988-97-8 6,6-dimethyl-2-methylene-(1(Z)-methylthio-1,3-butadiene)-1-yl cyclohexane 
• 67-56-1 methanol 

Downstream Products

• 31191-93-2 2-methylene-6,6-dimethyl-1-[but-2-enoyl]-cyclohexane 

Relevant articles and documents

HYDROLYSE ACIDO-CATALYSEE D'UN SULFURE DE DIENYLE APPLICATION A LA SYNTHESE DE LA gamma-DAMSCONE

A new synthetic route to γ-Damascone 1 starting with methyl-γ-dithiocyclogeranate 2 is described.Addition of HMPT was found necessary to perform the carbophilic addition of allylmagnesium bromide on dithioester 2.A dienylsulfide, 6,6-dimethyl-2-methylene-(1-methylthio-1,3-butadiene)-1-yl cyclohexane 3 resulted from this addition, and not the expected dithioketal.Following a number of described conditions, hydrolysis of 3 to γ-damascone 1 proved to be unsatisfactory.These initial attempts but showed the necessity for an acidic medium.This finding allowed the development of a new, very mild method of hydrolysis of dienylsulfides to unsaturated ketones.