19962-27-7

Basic information

• Product Name: Benzene, 1-methyl-4-(phenoxymethyl)-
• CAS NO: 19962-27-7
• Molecular Formula: C14H14O
• Molecular Weight: 198.265
• Mol File: 19962-27-7.mol
• Article Data: 8

Chemical Properties

• CAS DataBase Reference: Benzene, 1-methyl-4-(phenoxymethyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1-methyl-4-(phenoxymethyl)-(19962-27-7)
• EPA Substance Registry System: Benzene, 1-methyl-4-(phenoxymethyl)-(19962-27-7)

Safety Data

• Hazardous Substances Data: 19962-27-7(Hazardous Substances Data)

Upstream product

• 591-50-4 iodobenzene 
• 589-18-4 4-Methylbenzyl alcohol 
• 106-42-3 para-xylene 
• 122-79-2 Phenyl acetate 
• 104-81-4 4-Methylbenzyl bromide 
• 108-95-2 phenol 
• 104-82-5 4-Methylbenzyl chloride 
• 139-02-6 sodium phenoxide 
• 1517-63-1 4-methylphenyl(phenyl)methanol 
• 62-53-3 aniline 
• 104-87-0 4-methyl-benzaldehyde 

Downstream Products

• 6425-41-8 N-cyclohexylmorpholine 
• 1900-85-2 phenyl p-methylbenzoate 
• 104-87-0 4-methyl-benzaldehyde 
• 108-95-2 phenol 
• 2571-00-8 4-methylbenzaldehyde 2,4-dinitrophenylhydrazone 

Relevant articles and documents

CoII Immobilized on Aminated Magnetic-Based Metal–Organic Framework: An Efficient Heterogeneous Nanostructured Catalyst for the C–O Cross-Coupling Reaction in Solvent-Free Conditions

Abstract: In this paper, we report the synthesis of Fe3O4?AMCA-MIL53(Al)-NH2-CoII NPs based on the metal–organic framework structures as a magnetically separable and environmentally friendly heterogeneous nanocatalyst. The prepared nanostructured catalyst efficiently promotes the C–O cross-coupling reaction in solvent-free conditions without the need for using toxic solvents and/or expensive palladium catalyst. Graphic Abstract: [Figure not available: see fulltext.].

Tetrabutyl ammonium bromide-mediated benzylation of phenols in water under mild condition

Benzylation of phenol was successfully achieved in water under room temperature mediated by tetrabutylammonium bromide (TBAB) for only 2 h affording the corresponding benzyl phenyl ether with good to excellent yields. This protocol is very efficient, simple, avoiding catalysts, easy to work-up after reaction, and especially 'green'.

Ionic liquids as reagent and reaction medium: Preparation of alkyl aryl ethers

Room temperature ionic liquid, [bmIm]OH, is used as a green recyclable reaction medium and reagent for the alkylation of phenols in excellent yields. The recovered ionic liquid was reused five to six times with consistent activity.