2016-39-9

Basic information

• Product Name: NONYLAMINEHYDROCHLORIDE
• Synonyms: NONYLAMINEHYDROCHLORIDE
• CAS NO: 2016-39-9
• Molecular Formula: C9H21 N . Cl H
• Molecular Weight: 0
• Mol File: 2016-39-9.mol
• Article Data: 5

Chemical Properties

• Melting Point: 185-186 °C
• Boiling Point: 201.1°Cat760mmHg
• Flash Point: 62.8°C
• Appearance: /
• Density: g/cm³
• CAS DataBase Reference: NONYLAMINEHYDROCHLORIDE(CAS DataBase Reference)
• NIST Chemistry Reference: NONYLAMINEHYDROCHLORIDE(2016-39-9)
• EPA Substance Registry System: NONYLAMINEHYDROCHLORIDE(2016-39-9)

Safety Data

• Hazardous Substances Data: 2016-39-9(Hazardous Substances Data)

Upstream product

• 124-19-6 nonan-1-al 
• 112-12-9 methyl nonyl ketone 
• 2216-21-9 1-nitrononane 
• 2243-27-8 nonanonitrile 

Relevant articles and documents

Old Concepts, New Application – Additive-Free Hydrogenation of Nitriles Catalyzed by an Air Stable Alkyl Mn(I) Complex

An efficient additive-free manganese-catalyzed hydrogenation of nitriles to primary amines with molecular hydrogen is described. The pre-catalyst, a well-defined bench-stable alkyl bisphosphine Mn(I) complex fac-[Mn(dpre)(CO)3(CH3)] (dpre=1,2-bis(di-n-propylphosphino)ethane), undergoes CO migratory insertion into the manganese-alkyl bond to form acyl complexes which upon hydrogenolysis yields the active coordinatively unsaturated Mn(I) hydride catalyst [Mn(dpre)(CO)2(H)]. A range of aromatic and aliphatic nitriles were efficiently and selectively converted into primary amines in good to excellent yields. The hydrogenation of nitriles proceeds at 100 °C with a catalyst loading of 2 mol % and a hydrogen pressure of 50 bar. Mechanistic insights are provided by means of DFT calculations. (Figure presented.).

Reduction of aromatic and aliphatic nitro groups to anilines and amines with hypophosphites associated with Pd/C

The reduction of aromatic and aliphatic nitro groups to anilines and amines is performed with good yield and selectivity in short reaction times. A mixture of sodium hypophosphite and phosphinic acid is used in the presence of a heterogeneous catalyst 2.5 mol% of Pd/C (5%) in a biphasic water/2-MeTHF system.

Protecting-group-free synthesis of amines: Synthesis of primary amines from aldehydes via reductive amination

New methodology for the protecting-group-free synthesis of primary amines is presented. By optimizing the metal hydride/ammonia mediated reductive amination of aldehydes and hemiacetals, primary amines were selectively prepared with no or minimal formation of the usual secondary and tertiary amine byproduct. The methodology was performed on a range of functionalized aldehyde substrates, including in situ formed aldehydes from a Vasella reaction. These reductive amination conditions provide a valuable synthetic tool for the selective production of primary amines in fewer steps, in good yields, and without the use of protecting groups.