201932-61-8

Basic information

• Product Name: (E)-β-(N-hydroxyimino)propyldiphenylphosphine oxide
• Synonyms: (E)-β-(N-hydroxyimino)propyldiphenylphosphine oxide
• CAS NO: 201932-61-8
• Molecular Weight: 273.271
• Mol File: 201932-61-8.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: (E)-β-(N-hydroxyimino)propyldiphenylphosphine oxide(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-β-(N-hydroxyimino)propyldiphenylphosphine oxide(201932-61-8)
• EPA Substance Registry System: (E)-β-(N-hydroxyimino)propyldiphenylphosphine oxide(201932-61-8)

Safety Data

• Hazardous Substances Data: 201932-61-8(Hazardous Substances Data)

Upstream product

• 4559-70-0 Diphenylphosphine oxide 
• 671-59-0 chloroacetone oxime 
• 13172-76-4 diphenyl(propa-1,2-dien-1-yl)phosphine oxide 

Downstream Products

• 945483-74-9 C₁₅H₁₇N₂O₂P 
• 1147864-15-0 3-(diphenylphosphoryl)-2,5-dimethyl-4,5,6,7-tetrahydro-1H-indol-1-ol 
• 1147864-13-8 ethyl 4-(diphenylphosphoryl)-1-hydroxy-5-methyl-2-phenyl-1H-pyrrole-3-carboxylate 
• 1147864-07-0 3-(diphenylphosphoryl)-4-isopropyl-2-methyl-1H-pyrrol-1-ol 
• 945483-72-7 1-bromo-1-(diphenylphosphinoyl) propan-2-one oxime 
• 945483-93-2 C₁₅H₁₄NO₂P 
• 945483-87-4 2-[1-(diphenylphosphinoyl)-2-(hydroxyimino)propylamino]-3-phenylpropionic acid methyl ester 
• 945483-85-2 2-[1-(diphenylphosphinoyl)-2-(hydroxyimino)propylamino]-3-methylbutyric acid ethyl ester 
• 945483-84-1 [1-(diphenylphosphinoyl)-2-(hydroxyimino)propylamino]acetic acid ethyl ester 
• 945483-79-4 1-(diphenylphosphinoyl)-1-(prop-2-ynylamino)propan-2-one oxime 

Relevant articles and documents

Michael Addition of P-Nucleophiles to Conjugated Nitrosoalkenes

A general approach to various α-phosphorus-substituted oximes (β-oximinoalkyl-substituted phosphonates, phosphine oxides, phosphine-borane complexes, and phosphonium salts) was developed. The strategy exploits hitherto unknown Michael addition of PH-containing compounds (diphenylphosphine oxide, diisopropyl phosphite, phosphine-borane complexes, and triphenylphosphonium bromide) to unstable conjugated nitrosoalkenes, which are generated in situ from corresponding nitrosoacetals. The resulting α-phosphorus-substituted oximes can be considered as useful P-, N-, and O-ligands for catalysis and precursors to valuable β-aminophosphonates.

Simple asymmetric synthesis of 2H-azirines derived from phosphine oxides

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