671-59-0

Basic information

• Product Name: 1-Chloro-2-propanone oxime
• Synonyms: 1-Chloro-2-propanone oxime
• CAS NO: 671-59-0
• Molecular Formula: C₃H₆ClNO
• Molecular Weight: 107.5388
• Mol File: 671-59-0.mol
• Article Data: 4

Chemical Properties

• Boiling Point: 194.5°Cat760mmHg
• Flash Point: 71.4°C
• Appearance: /
• Density: 1.18g/cm³
• Vapor Pressure: 0.191mmHg at 25°C
• Refractive Index: 1.457
• PKA: 11.45±0.10(Predicted)
• CAS DataBase Reference: 1-Chloro-2-propanone oxime(CAS DataBase Reference)
• NIST Chemistry Reference: 1-Chloro-2-propanone oxime(671-59-0)
• EPA Substance Registry System: 1-Chloro-2-propanone oxime(671-59-0)

Safety Data

• Hazardous Substances Data: 671-59-0(Hazardous Substances Data)

Usage

Appearance

White crystalline solid

Odor

Strong ammonia-like

Usage

a. Synthesis of pharmaceuticals
b. Synthesis of agrochemicals
c. Intermediate in the production of other organic compounds

Chemical reactions

a. Hydrolysis
b. Oxidation

Safety precautions

a. Harmful if ingested
b. Harmful if inhaled
c. Harmful if absorbed through the skin
d. Causes irritation to the respiratory system
e. Causes irritation to the eyes

InChI:InChI=1/C3H6ClNO/c1-3(2-4)5-6/h6H,2H2,1H3/b5-3-

Upstream product

• 78-95-5 chloroacetone 
• 92767-25-4 3-chloro-2-methyl-2-nitroso-propionaldehyde N,N'-dimer 
• 7803-49-8 hydroxylamine 

Downstream Products

• 63442-69-3 1-Piperidino-2-propanon-oxim 
• 2911-43-5 chloro-acetone-(O-phenylcarbamoyl oxime ) 
• 17631-12-8 (2-hydroxyimino-propyl)-triphenyl-phosphonium; chloride 
• 34683-69-7 dimethyl-dithiocarbamic acid-(2-hydroxyimino-propyl ester) 
• 93752-12-6 2-(hydroxyimino)propyl dithiobenzoate 
• 827-43-0 4-methyl-2-phenyl-1H-imidazole 
• 100-61-8 N-methylaniline 
• 1236132-60-7 C₁₀H₁₁NO₂Te 
• 673-55-2 (E)-dimethylamino-acetone oxime 
• 201932-61-8 (E)-β-(N-hydroxyimino)propyldiphenylphosphine oxide 

Relevant articles and documents

High-Throughput Screening of the Alkoxide/Oxime-Based Library: An Alternative to Organotin Compounds for the Alkoxysilane Condensation in Adhesives and Sealants

In this work, a high-throughput screening (HTS) method was used to discover new efficient catalysts to substitute organotin compounds (DBTDL) for the cross-linking of silyl-modified polymers (SMPs). We report here on the use of our HTS method to investigate a library of alkoxide/oxime systems with different metal/ligand (M/L) ratios. Among the 156 candidates tested, 40 interesting hits were detected. Then, the cross-linking times for the better hits were measured on the SMP. Some of these seem to be more efficient than DBTDL and exhibit a good stability during storage in cartridges. Thereby, a high efficiency of alkoxide/oxime systems was established that shows great potential for the generation of new ligands to provide new tin-free catalysts for the cross-linking of adhesives and sealants.

Oxime compounds, their use, and intermediates for their production

Oxime compounds of formula (1) wherein R1, R2, and R3 are independently halogen, C1-C3 alkyl, C1-C3 halolalkyl, C1-C3 alkoxy, C1-C3 haloalkoxy, nitro, or cyano; R4 is 3,3-dihalogeno-2-propenyl; a is an integer of 0 to 2; Y is oxygen, sulfur, or NH; Z is oxygen, sulfur, or NR5wherein R5 is hydrogen, acetyl, or C1-C3 alkyl; and X is of formula (2) insecticidal/acaricidal agents containing them as active ingredients; and intermediates for their production.