202392-39-0

Basic information

• Product Name: ((2R,3R,5R)-5-Allyl-3-methyl-tetrahydro-furan-2-ylmethoxy)-tert-butyl-diphenyl-silane
• CAS NO: 202392-39-0
• Molecular Weight: 394.629
• Mol File: 202392-39-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: ((2R,3R,5R)-5-Allyl-3-methyl-tetrahydro-furan-2-ylmethoxy)-tert-butyl-diphenyl-silane(CAS DataBase Reference)
• NIST Chemistry Reference: ((2R,3R,5R)-5-Allyl-3-methyl-tetrahydro-furan-2-ylmethoxy)-tert-butyl-diphenyl-silane(202392-39-0)
• EPA Substance Registry System: ((2R,3R,5R)-5-Allyl-3-methyl-tetrahydro-furan-2-ylmethoxy)-tert-butyl-diphenyl-silane(202392-39-0)

Safety Data

• Hazardous Substances Data: 202392-39-0(Hazardous Substances Data)

Upstream product

• 762-72-1 allyl-trimethyl-silane 
• 112837-17-9 (R)-(+)-5-(hydroxymethyl)furan-2(5H)-one 
• 58479-61-1 tert-butylchlorodiphenylsilane 
• 110098-09-4 (4R,5R)-5-(tert-Butyl-diphenyl-silanyloxymethyl)-4-methyl-dihydro-furan-2-one 
• 110171-24-9 (R)-(+)-5-(tert-butyldiphenylsilanyloxymethyl)furan-2(5H)-one 
• 106757-56-6 (Z)-(-)-methyl 3-((R)-2,2-dimethyl-1,3-dioxolan-4-yl)acrylate 

Downstream Products

• 202392-41-4 tert-Butyl-[(2R,3R,5R)-5-(3-methoxymethoxy-propyl)-3-methyl-tetrahydro-furan-2-ylmethoxy]-diphenyl-silane 
• 202392-40-3 3-[(2R,4R,5R)-5-(tert-Butyl-diphenyl-silanyloxymethyl)-4-methyl-tetrahydro-furan-2-yl]-propan-1-ol 

Relevant articles and documents

Synthetic study on gymnodimine: Highly stereoselective construction of substituted tetrahydrofuran and cyclohexene moieties

The synthetic studies on gymnodimine, a shellfish toxin, are described. This marine toxin consists of 16-membered carbocycle, tetrahydrofuran, and spiro-imine moieties. Our synthetic strategy involves the stereoselective allylation of tetrahydrofuran compound and the exo-selective intramolecular Diels-Alder reaction.