2027-54-5

Basic information

• Product Name: 2-fluoro-N-phenylbenzenecarbothioamide
• CAS NO: 2027-54-5
• Molecular Formula: C₁₃H₁₀FNS
• Molecular Weight: 231.2886
• Mol File: 2027-54-5.mol
• Article Data: 3

Chemical Properties

• Boiling Point: 332.6°C at 760 mmHg
• Flash Point: 154.9°C
• Density: 1.282g/cm³
• Vapor Pressure: 0.000145mmHg at 25°C
• Refractive Index: 1.678
• CAS DataBase Reference: 2-fluoro-N-phenylbenzenecarbothioamide(CAS DataBase Reference)
• NIST Chemistry Reference: 2-fluoro-N-phenylbenzenecarbothioamide(2027-54-5)
• EPA Substance Registry System: 2-fluoro-N-phenylbenzenecarbothioamide(2027-54-5)

Safety Data

• Hazardous Substances Data: 2027-54-5(Hazardous Substances Data)

Upstream product

• 1747-80-4 2-fluoro-N-phenylbenzamide 
• 62-53-3 aniline 
• 393-52-2 2-Fluorobenzoyl chloride 

Downstream Products

• 1747-46-2 2-(2-fluorophenyl)-1,3-benzothiazole 
• 835-42-7 (1H-indazol-3-yl)(phenyl)amine 

Relevant articles and documents

Visible-Light Carbon Nitride-Catalyzed Aerobic Cyclization of Thiobenzanilides under Ambient Air Conditions

A metal-free heterogeneous photocatalysis has been developed for the synthesis of benzothiazoles via intramolecular C-H functionalization/C-S bond formation of thiobenzanilides by inexpensive graphitic carbon nitride (g-C3N4) under visible-light irradiation. This reaction provides access to a broad range of 2-substituted benzothiazoles in high yields under an air atmosphere at room temperature without addition of a strong base or organic oxidizing reagents. In addition, the catalyst was found to be stable and reusable after five reaction cycles.

An efficient route to 3-aminoindazoles and 3-amino-7-azaindazoles

A non-acidic procedure for the preparation of 3-aminoindazoles and 3-amino-7-azaindazoles from 2-fluoroaryl carboxylic acids is reported. The synthesis starts from readily available starting materials and uses mild and practical reaction conditions in a three-step overall procedure. Products were isolated for a number of examples, but yields varied significantly depending on electronic nature of the substituents.