203321-89-5

Basic information

• Product Name: (3,5-dimethylphenyl)carbamic acid 1,1-dimethylethyl ester
• Synonyms: (3,5-dimethylphenyl)carbamic acid 1,1-dimethylethyl ester
• CAS NO: 203321-89-5
• Molecular Weight: 221.299
• Mol File: 203321-89-5.mol
• Article Data: 7

Chemical Properties

• CAS DataBase Reference: (3,5-dimethylphenyl)carbamic acid 1,1-dimethylethyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: (3,5-dimethylphenyl)carbamic acid 1,1-dimethylethyl ester(203321-89-5)
• EPA Substance Registry System: (3,5-dimethylphenyl)carbamic acid 1,1-dimethylethyl ester(203321-89-5)

Safety Data

• Hazardous Substances Data: 203321-89-5(Hazardous Substances Data)

Usage

Description

(3,5-dimethylphenyl)carbamic acid 1,1-dimethylethyl ester, commonly known as terbuthylazine, is a chemical compound belonging to the triazine herbicide group. It is used as an effective herbicide for controlling both grasses and broadleaf weeds in various crops. Terbuthylazine functions by inhibiting the photosynthesis process in target plants, leading to their death. It exhibits low to moderate toxicity and is relatively stable in the environment, making it a popular choice for weed control in agricultural and horticultural settings. However, it is crucial to use this chemical with caution and in accordance with the recommended guidelines to minimize any potential adverse effects on the environment and human health.

Uses

Used in Agricultural Industry:
(3,5-dimethylphenyl)carbamic acid 1,1-dimethylethyl ester is used as a herbicide for controlling grasses and broadleaf weeds in various crops. It is effective in ensuring the healthy growth of crops by eliminating unwanted weeds that compete for nutrients and sunlight.
Used in Horticultural Industry:
(3,5-dimethylphenyl)carbamic acid 1,1-dimethylethyl ester is used as a herbicide in horticultural settings to maintain the aesthetic appeal and health of gardens, landscapes, and other cultivated areas. By controlling weeds, it helps in preserving the visual appeal and overall well-being of the plants in these settings.

Upstream product

• 24424-99-5 di-tert-butyl dicarbonate 
• 108-69-0 3,5-dimethylaminoaniline 
• 54132-75-1 3,5-dimethylphenyl isocyanate 
• 75-65-0 tert-butyl alcohol 
• 4406-77-3 2-Phenyl-1,3,2-dioxaborinane 
• 499-06-9 3,5-dimethylbenzoic acid 

Downstream Products

• 329938-23-0 N-(3,5-dimethylphenyl)-2-methylbenzamide 
• 25050-22-0 N-(3,5-dimethylphenyl)-benzamide 
• 127291-98-9 N-(3,5-dimethylphenyl)-4-methoxybenzamide 
• 127292-04-0 N-(3,5-dimethylphenyl)-4-chlorobenzamide 
• 346663-67-0 N-(3,5-dimethylphenyl)-4-bromobenzamide 
• 544450-47-7 N-(3,5-dimethylphenyl)-1-naphthamide 
• 346725-77-7 N-(3,5-dimethylphenyl)-4-tert-butyl-benzamide 
• 102631-08-3 N-(3,5-dimethylphenyl)-3-nitrobenzamide 
• 54132-75-1 3,5-dimethylphenyl isocyanate 
• 346721-60-6 N-(3,5-dimethylphenyl)-3-methoxybenzamide 

Relevant articles and documents

Efficient and expeditious chemoselective BOC protection of amines in catalyst and solvent-free media

A green and eco-friendly route for the almost quantitative BOC protection of a large variety of aliphatic and aromatic amines, amino acids, and amino alcohols is reported in catalyst and solvent-free media under mild reaction conditions. The products were confirmed by 1H, 13C NMR, IR spectroscopy, and in some cases, elemental analysis. This protocol does not require any water quenches, solvent separations, and purification steps, such as recrystallization and column chromatography.

Direct Amidation of N-Boc- and N-Cbz-Protected Amines via Rhodium-Catalyzed Coupling of Arylboroxines and Carbamates

N-Boc- and N-Cbz-protected amines are directly converted into amides by a novel rhodium-catalyzed coupling of arylboroxines and carbamates, replacing the traditional two-step deprotection-condensation sequence. Both protected anilines and aliphatic amines are efficiently transformed into a wide variety of secondary benzamides, including sterically hindered and electron-deficient amides, as well as in the presence of acid-labile and reducible functional groups.

Synthesis of indolines, indoles, and benzopyrrolizidinones from simple aryl azides

A simple approach to prepare indolines and benzopyrrolizidinones from ortho-azidoallylbenzenes via a tandem radical addition/cyclization is described. The use of triethylborane to initiate and sustain the process provides the best results. Indolines are easily converted into the corresponding indoles by oxidation with manganese dioxide.