20351-71-7

Basic information

• Product Name: Carbamothioic acid, methylphenyl-, O-phenyl ester
• Synonyms: Carbamothioic acid,methylphenyl-,O-phenyl ester;methyl-phenyl-thiocarbamic acid O-phenyl ester;O-phenyl N-methyl-N-phenylthiocarbamate;N-Methyl-thiocarbanilsaeure-O-phenylester;Methyl-phenyl-thiocarbamidsaeure-O-phenylester
• CAS NO: 20351-71-7
• Molecular Formula: C14H13NOS
• Molecular Weight: 243.329
• Mol File: 20351-71-7.mol
• Article Data: 8

Chemical Properties

• CAS DataBase Reference: Carbamothioic acid, methylphenyl-, O-phenyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Carbamothioic acid, methylphenyl-, O-phenyl ester(20351-71-7)
• EPA Substance Registry System: Carbamothioic acid, methylphenyl-, O-phenyl ester(20351-71-7)

Safety Data

• Hazardous Substances Data: 20351-71-7(Hazardous Substances Data)

Upstream product

• 100-61-8 N-methylaniline 
• 1005-56-7 phenylcarbonochloridothioate 
• 121-69-7 N,N-dimethyl-aniline 
• 108-95-2 phenol 
• 463-71-8 thiophosgene 

Downstream Products

• 1934-92-5 N-methyl-N-phenyl-benzamide 

Relevant articles and documents

First-class amine thioformate derivative and synthesis method thereof

The invention discloses a first-class amine thioformate derivative and a synthesis method thereof. The derivative has a structure shown as a formula (I). According to the synthesis method, amine thionyl fluoride is used as raw materials; copper salt is us

Lewis base catalysis by thiourea: N -bromosuccinimide-mediated oxidation of alcohols

In recent times, (thio)urea derivatives have become synonymous with hydrogen bonding owing to their extensive applicability as small molecule organocatalysts. In this paper, another activation mode by thiourea derivatives, namely via Lewis base catalysis, is disclosed for the NBS-mediated oxidation of alcohols. The mild reaction conditions employed here is suitable for chemoselective oxidation of secondary alcohol in the presence of primary alcohol.

DIRECT CONVERSION OF PHENOLS INTO AMIDES AND ESTERS OF BENZOIC ACID

A method is provided for the preparation of an aromatic carboxylic acid aryl ester or an N-aryl aromatic carboxamide. The method comprises contacting an O,O-diaryl thiocarbonate or an O-aryl-N-aryl thiocarbamate with a reactant that regioselectively reacts with sulfur, which contact causes an O-neophyl rearrangement, thereby forming either the aromatic carboxylic acid aryl ester or the N-aryl aromatic carboxamide, respectively.