203726-07-2

Basic information

• Product Name: (2Z)-(+)-ethyl 2-methyl-3-[(S)-α-methylbenzylamino]-2-pentenoate
• Synonyms: (2Z)-(+)-ethyl 2-methyl-3-[(S)-α-methylbenzylamino]-2-pentenoate
• CAS NO: 203726-07-2
• Molecular Weight: 261.364
• Mol File: 203726-07-2.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (2Z)-(+)-ethyl 2-methyl-3-[(S)-α-methylbenzylamino]-2-pentenoate(CAS DataBase Reference)
• NIST Chemistry Reference: (2Z)-(+)-ethyl 2-methyl-3-[(S)-α-methylbenzylamino]-2-pentenoate(203726-07-2)
• EPA Substance Registry System: (2Z)-(+)-ethyl 2-methyl-3-[(S)-α-methylbenzylamino]-2-pentenoate(203726-07-2)

Safety Data

• Hazardous Substances Data: 203726-07-2(Hazardous Substances Data)

Upstream product

• 121811-29-8 ethyl 2-methyl-3-oxopentanoate 
• 2627-86-3 (S)-1-phenyl-ethylamine 

Downstream Products

• 203726-10-7 (S)-1,3-Dimethyl-2-oxo-cyclohex-3-enecarboxylic acid ethyl ester 
• 203726-18-5 (R)-6-Hydroxymethyl-2,6-dimethyl-cyclohex-2-enone 
• 123522-71-4 (6R)-4-(tert-butyldiphenylsilyloxymethyl)-2,6-dimethyl-2-cyclohexenone 
• 428454-90-4 (S)-(-)-ethyl 2-ethyl-1-methyl-4-oxo-2-cyclohexenecarboxylate 

Relevant articles and documents

Michael reaction of acyclic β-enaminoesters derived from α-alkyl-β-ketoesters and chiral α-methylbenzylamine: Stereoselective generation of quaternary carbon centres

Michael reaction of electrophilic olefins with acyclic β-enaminoester substrates derived from α-substituted β-ketoesters and (R)- or (S)-α-methylbenzylamine under neutral conditions resulted in the enantioselective formation of quaternary centres. The add