203731-09-3Relevant articles and documents
Cycloaddition reactions of diethyl (E)-2-fluoromaleate
Patrick, Timothy B.,Shadmehr, Mehrdad,Khan, Akbar H.,Singh, Rajiv K.,Asmelash, Bethel
, p. 109 - 111,3 (2012)
Diethyl E-2-fluoromaleate has been prepared in a pure state in 89% yield by a Horner-Wadsworth-Emmons Wittig procedure. The E configuration was determined by NMR spectroscopy. Diethyl E-2-fluoromaleate undergoes [3+2] cycloadditions with a series of aroma
Carbamoylation of Azomethine Imines via Visible-Light Photoredox Catalysis
Correia, José Tiago M.,Matsuo, Bianca T.,Oliveira, Pedro H. R.,Paix?o, Márcio W.
supporting information, p. 6775 - 6779 (2021/09/13)
A versatile and robust photocatalytic methodology to install the amide functional group into azomethine imine ions is described. This protocol is distinguished by its broad scope and mild reaction conditions, which are well suited for the preparation of s
BPh3-Catalyzed [2+3] Cycloaddition of Ph3PCCO with Aldonitrones: Access to 5-Isoxazolidinones with Exocyclic Phosphonium Ylide Moieties
Brar, Amandeep,Unruh, Daniel K.,Ling, Natalie,Krempner, Clemens
, p. 6305 - 6309 (2019/08/20)
A method for the generation of 5-isoxazolidinones with exocyclic phosphonium ylide functionalities via [2+3] cycloaddition of Ph3PCCO and aldonitrones has been developed and applied in the synthesis of 4-alkylidene-5-isoxazolidinones via Wittig olefination. The reaction proceeds by BPh3 catalysis under mild conditions and with a broad substrate scope. A reaction pathway involving the activation of the aldonitrone via interactions with the Lewis acid BPh3 is proposed.
A highly diastereoselective [3+3] annulation reaction of aza-oxyallyl cations and nitrones
Chen, Rongxing,Sun, Shaofa,Wang, Gangqiang,Guo, Haibin
supporting information, p. 1916 - 1920 (2018/04/19)
An efficient synthesis of 1,2,4-oxadiazinan-5-ones via [3+3] cycloaddition of in situ generated aza-oxyallyl cations with nitrones has been developed. The protocol features easy operation, excellent yields, excellent diastereo-control, broad substrate sco