2039-44-3

Basic information

• Product Name: BETA-STYRENESULFONIC ACID SODIUM SALT
• Synonyms: SODIUM BETA-STYRENESULFONATE;BETA-STYRENESULFONIC ACID SODIUM SALT;?Styrenesulfonic acid sodium salt;Styrenesulfonicacidsodiumsalt;sodium 2-phenylethylene-1-sulphonate;SS-STYRENESULFONIC ACID SODIUM SALT;2-Phenylethenesulfonic acid sodium salt;Sodium β-styrenesulfonate
• CAS NO: 2039-44-3
• Molecular Formula: C8H7NaO3S
• Molecular Weight: 206.19
• EINECS: 218-013-7
• Mol File: 2039-44-3.mol
• Article Data: 2

Chemical Properties

• Appearance: /
• Water Solubility: Soluble in water
• CAS DataBase Reference: BETA-STYRENESULFONIC ACID SODIUM SALT(CAS DataBase Reference)
• NIST Chemistry Reference: BETA-STYRENESULFONIC ACID SODIUM SALT(2039-44-3)
• EPA Substance Registry System: BETA-STYRENESULFONIC ACID SODIUM SALT(2039-44-3)

Safety Data

• Hazardous Substances Data: 2039-44-3(Hazardous Substances Data)

Usage

Synthesis Reference(s)

Tetrahedron Letters, 12, p. 351, 1971 DOI: 10.1016/S0040-4039(01)96439-1

InChI:InChI=1/C8H8O3S.Na/c9-12(10,11)7-6-8-4-2-1-3-5-8;/h1-7H,(H,9,10,11);/q;+1/p-1/b7-6+;

Upstream product

• 4091-26-3 β-styrenesulfonyl chloride 
• 100-42-5 styrene 
• 591-50-4 iodobenzene 
• 1622-32-8 2-Chloroethanesulfonyl chloride 

Downstream Products

• 97273-00-2 2-Cyclohexylamino-2-phenylethansulfonsaeure 
• 97272-98-5 2-Ethylamino-2-phenylethansulfonsaeure 
• 97272-96-3 2-amino-2-phenylethanesulfonic acid 
• 97272-97-4 2-Methylamino-2-phenylethansulfonsaeure 
• 97273-01-3 2-Benzylamino-2-phenylethansulfonsaeure 
• 94287-18-0 (RS)-2-methyl-3-phenyl-1,2-thiazetidine 1,1-dioxide 
• 97273-02-4 3-phenyl-1,2-thiazetidine 1,1-dioxide 
• 94287-19-1 2-Ethyl-3-phenyl-1,2-thiazetidin-1,1-dioxid 
• 94287-21-5 2-Isopropyl-3-phenyl-1,2-thiazetidin-1,1-dioxid 
• 94287-20-4 2-Benzyl-3-phenyl-1,2-thiazetidin-1,1-dioxid 
• 97273-03-5 2-Cyclohexyl-3-phenyl-1,2-thiazetidin-1,1-dioxid 

Relevant articles and documents

A domino approach (hydrolysis/dehydrohalogenation/heck coupling) for the synthesis of styrene sulfonate salts

A domino approach of hydrolysis/dehydrohalogenation/Heck coupling was used to synthesize styrene sulfonate salts from iodoarenes and chloroethanesulfonyl chloride in good to excellent yields. Methodology was applicable for heterocyclic as well as disubstituted iodoarenes. Some of the key features of this synthetic methodology include the use of phosphine free catalytic system, water as an environmentally friendly solvent, short reaction times, and absence of additives.