2046-21-1Relevant articles and documents
Iron-catalyzed oxidative functionalization of C(sp3)-H bonds under bromide-synergized mild conditions
Yu, Han,Zhao, Qixin,Wei, Zheyu,Wu, Zhikang,Li, Qi,Han, Sheng,Wei, Yongge
supporting information, p. 7840 - 7843 (2019/07/12)
An efficient oxidation and functionalization of C-H bonds with an inorganic-ligand supported iron catalyst and hydrogen peroxide to prepare the corresponding ketones was achieved using the bromide ion as a promoter. Preliminary mechanistic investigations indicated that the bromide ion can bind to FeMo6 to form a supramolecular species (FeMo6·2Br), which can effectively catalyze the reaction.
Reaction of 3,5-disubstituted 4,5-dihydroisoxazoles with hexacarbonylmolybdenum
Koroleva,Katok,Lakhvich
, p. 1003 - 1008 (2007/10/03)
Depending on the reaction conditions and structure of the 5-substituent, reactions of substituted 4,5-dihydroisoxazoles with hexacarbonylmolybdenum involve cleavage of the heteroring at the N-O bond, its aromatization, or/and 1,3-decyclization.
Oxidative Cleavage of Olefins into Carboxylic Acids with Hydrogen Peroxide by Tungstic Acid
Oguchi, Takahito,Ura, Toshikazu,Ishii, Yasutaka,Ogawa, Masaya
, p. 857 - 860 (2007/10/02)
A facile conversion of olefins into carboxylic acids could be achieved by using aqueous hydrogen peroxide (35percent-H2O2) in the presence of catalytic amounts of tungstic acid (5 wtpercent).The oxidation was markedly influenced by the acidity of the reaction medium, and it was found to proceed favorably under a weak acidic condition (pH 4-5).