20502-36-7

Basic information

• Product Name: Bis(dimethylamino)bromophosphine
• Synonyms: Bis(dimethylamino)bromophosphine
• CAS NO: 20502-36-7
• Molecular Formula: C₄H₁₂BrN₂P
• Molecular Weight: 199.03
• Mol File: 20502-36-7.mol
• Article Data: 1

Chemical Properties

• Appearance: /
• CAS DataBase Reference: Bis(dimethylamino)bromophosphine(CAS DataBase Reference)
• NIST Chemistry Reference: Bis(dimethylamino)bromophosphine(20502-36-7)
• EPA Substance Registry System: Bis(dimethylamino)bromophosphine(20502-36-7)

Safety Data

• Hazardous Substances Data: 20502-36-7(Hazardous Substances Data)

Upstream product

• 114253-39-3 (Bis-dimethylamino-phosphino)-bis-dimethylamino-phosphin 
• 1608-26-0 Hexamethylphosphorous triamide 
• 2857-97-8 trimethylsilyl bromide 

Relevant articles and documents

INTERACTION OF P(III) COMPOUNDS WITH SILYL HALIDES. THE MECHANISM OF THE REACTION OF PHOSPHOROUS TRIAMIDES WITH TRIALKYLSILYL HALIDES

The reaction of phosphorous hexamethyltriamide with trimethylsilyl iodide or bromide provides a convenient synthesis of the corresponding N,N,N',N'-tetramethylphosphorodiamidous halide.Low temperature (31)P NMR studies gave evidence of the formation of a phosphonium salt-type complex with direct P-Si bonding in the first step of the reaction. Analogous phosphonium salt intermediates involving P-P bonds were found to be involved in some ligand exchange process between two tricoordinated phosphorus species.