206987-22-6

Basic information

• Product Name: Dimethyl-(7-methyl-octa-1,2,7-trienyl)-phenyl-silane
• Synonyms: Dimethyl-(7-methyl-octa-1,2,7-trienyl)-phenyl-silane
• CAS NO: 206987-22-6
• Molecular Weight: 256.463
• Mol File: 206987-22-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Dimethyl-(7-methyl-octa-1,2,7-trienyl)-phenyl-silane(CAS DataBase Reference)
• NIST Chemistry Reference: Dimethyl-(7-methyl-octa-1,2,7-trienyl)-phenyl-silane(206987-22-6)
• EPA Substance Registry System: Dimethyl-(7-methyl-octa-1,2,7-trienyl)-phenyl-silane(206987-22-6)

Safety Data

• Hazardous Substances Data: 206987-22-6(Hazardous Substances Data)

Upstream product

• 768-33-2 phenyldimethylsilyl chloride 
• 206987-21-5 Acetic acid 1-ethynyl-5-methyl-hex-5-enyl ester 
• 206987-20-4 7-Methyl-oct-7-en-1-yn-3-ol 
• 10412-98-3 5-oxohexanenitrile 
• 50592-60-4 5-methylhex-5-enenitrile 
• 64825-78-1 5-methyl-5-hexen-1-al 

Relevant articles and documents

Thermal and lewis acid catalyzed intramolecular ene reactions of allenylsilanes

Intramolecular ene reactions of allenylsilanes can be effected with a variety of imines, aldehydes and alkenes as enophiles, forming five and six membered rings. These reactions are cis stereoselective in all cases studied, and appear to proceed via a concerted, pericyclic process. The cycloadditions all generally occur under mild thermal conditions and some involving imino enophiles can also be effected at lower temperatures using Lewis acid catalysis.