208333-25-9

Basic information

• Product Name: [(1,10-phenanthroline)PtI(C₆H₅)]
• CAS NO: 208333-25-9
• Molecular Weight: 579.299
• Mol File: 208333-25-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [(1,10-phenanthroline)PtI(C₆H₅)](CAS DataBase Reference)
• NIST Chemistry Reference: [(1,10-phenanthroline)PtI(C₆H₅)](208333-25-9)
• EPA Substance Registry System: [(1,10-phenanthroline)PtI(C₆H₅)](208333-25-9)

Safety Data

• Hazardous Substances Data: 208333-25-9(Hazardous Substances Data)

Upstream product

• 208333-45-3 PtC₆H₅(NCCH₃)(C₁₂H₈N₂)⁽¹⁺⁾*BF₄^(1-) = [PtC₆H₅(NCCH₃)(C₁₂H₈N₂)]BF₄ 
• 7681-11-0 potassium iodide 

Downstream Products

• 1015066-14-4 [(1,10-phenanthroline)Pt(Ph)(2-butyne)]BF₄ 
• 208333-33-9 Pt(CH₂CHCH₃)(CH₂CH(CH₃)C₆H₅)(C₁₂H₈N₂)⁽¹⁺⁾*BF₄^(1-) = [Pt(CH₂CHCH₃)(CH₂CH(CH₃)C₆H₅)(C₁₂H₈N₂)]BF₄ 
• 208333-37-3 Pt(NCCH₃)(C₆H₄C₂H₅)(C₁₂H₈N₂)⁽¹⁺⁾*BF₄^(1-) = [Pt(NCCH₃)(C₆H₄C₂H₅)(C₁₂H₈N₂)]BF₄ 
• 208333-29-3 Pt(CH₂CHCH₃)(C₆H₅)(C₁₂H₈N₂)⁽¹⁺⁾*BF₄^(1-) = [Pt(CH₂CHCH₃)(C₆H₅)(C₁₂H₈N₂)]BF₄ 
• 208333-27-1 Pt(C₂H₄)(C₆H₅)(C₁₂H₈N₂)⁽¹⁺⁾*BF₄^(1-) = [Pt(C₂H₄)(C₆H₅)(C₁₂H₈N₂)]BF₄ 
• 18432-95-6 dichloro(1,10-phenanthroline)platinum(II) 
• 852673-90-6 [(1,10-phenanthroline)PtI(CH₂=CHCH₂C₆H₄)] 
• 852673-87-1 [(1,10-phenanthroline)PtI(CH₂CH(CH₂OH)C₆H₅)] 

Relevant articles and documents

Regiochemical control of a Pt-promoted alkylation of the phenyl ring

The reactivity of cationic PtII-phenyl complexes of the type [PtPh(CH2=CHR)(Phen)]+ (R = H or Me) has been investigated. In all cases, insertion of the alkene into the Pt-Ph bond has been observed. The fate of the resulting Pt-CH2CHRPh (R = H or Me) derivative depends on the experimental conditions. In the presence of donor ligands (e.g. excess olefin, pyridine or triphenylphosphine) the product is stable, while in the absence of them a rapid rearrangement to form Pt-C6H4(CHRMe)-2 occurs.