210821-60-6Relevant articles and documents
Kinetics of snar reactions of 1-phenoxy-nitrobenzenes with aliphatic amines in toluene: Ring substituent and solvent effects on reaction pathways
Isanbor, Chukwuemeka,Babatunde, Alice Ibitola
, p. 1078 - 1085 (2009)
Rate constants are reported for the reactions of a series of 4-substituted-1-phenoxy-2,6-dinitrobenzenes 1 and 6-substituted-1-phenoxy-2,4- dinitrobenzenes 2 activated by CF3, COOCH3, CN, NO 2 groups or by ring-nitrogen wi
Rapid scan spectrophotometric and kinetic studies in the reactions of 4-substituted-2,6-dinitro-N-n-butylanilines with n-butylamine in dimethyl sulfoxide
Hasegawa, Yoshinori
, p. 1561 - 1564 (1998)
The reactions of 2,4,6-trinitro-N-n-butylaniline 6a, 4-cyano-2,6-dinitro-N-n-butylaniline 6b and 4-methoxycarbonyl-2,6-dinitro-N-n-butylaniline 6c with n-butylamine in dimethyl sulfoxide have been investigated by rapid scan spectrophotometry and a stopped-flow method. 6a and 6b react competitively with n-butylamine to give the conjugate bases due to fast proton transfer and anionic σ-adducts by the addition of amine at the 3-position, while 6c reacts to give the conjugate base. The distinct spectra of only the conjugate bases have been observed. The effect of substituents on rate and equilibrium constants obtained for these competitive reactions is discussed.