221468-61-7

Basic information

• Product Name: (2S,5S,6S,9S,10S)-1-benzyloxy-2,5;6,9-diepoxy-10-(methoxymethoxy)tetracosane
• Synonyms: (2S,5S,6S,9S,10S)-1-benzyloxy-2,5;6,9-diepoxy-10-(methoxymethoxy)tetracosane
• CAS NO: 221468-61-7
• Molecular Weight: 532.805
• Mol File: 221468-61-7.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (2S,5S,6S,9S,10S)-1-benzyloxy-2,5;6,9-diepoxy-10-(methoxymethoxy)tetracosane(CAS DataBase Reference)
• NIST Chemistry Reference: (2S,5S,6S,9S,10S)-1-benzyloxy-2,5;6,9-diepoxy-10-(methoxymethoxy)tetracosane(221468-61-7)
• EPA Substance Registry System: (2S,5S,6S,9S,10S)-1-benzyloxy-2,5;6,9-diepoxy-10-(methoxymethoxy)tetracosane(221468-61-7)

Safety Data

• Hazardous Substances Data: 221468-61-7(Hazardous Substances Data)

Upstream product

• 107-30-2 chloromethyl methyl ether 
• 221468-04-8 (2S,5S,6S,9S,10S)-1-benzyloxy-2,5;6,9-diepoxy-10-tetracosanol 
• 39139-91-8 trans-1,5,9-decatriene 
• 100-39-0 benzyl bromide 
• 174645-23-9 (2S,5S,6S,9S)-2,5;6,9-diepoxydecane-1,10-diol 
• 221467-95-4 (5S,6S)-5,6-dihydroxydeca-1,9-diene 
• 221468-00-4 (2S,5S,2'S,5'S)-5'-Benzyloxymethyl-octahydro-[2,2']bifuranyl-5-carbaldehyde 
• 221468-58-2 (2S,5S,6S,9S)-1-benzyloxy-2,5;6,9-diepoxy-1-decanol 

Relevant articles and documents

A facile route to bulladecin-type acetogenins - Total synthesis of asimilobin and correction of the configuration of its tetrahydrofuran segment

The most efficient method for the synthesis of the trans/threo/trans- bis(tetrahydrofuran) (THF) ring unit was established, and the first total synthesis of (-)-asimilobin and its diastereomer was then accomplished in twelve and fourteen steps, respectively, from trans-1,5,9-decatriene, by a convergent route with a Wittig reaction as the key step. By virtue of these synthetic results, the absolute configuration of the bis(THF) unit in naturally occurring asimilobin should be corrected.