222533-60-0

Basic information

• Product Name: 2H-Indol-2-one, 1,3-dihydro-3-(3-methyl-2-butenyl)-1-(phenylmethyl)-
• CAS NO: 222533-60-0
• Molecular Formula: C20H21NO
• Molecular Weight: 291.393
• Mol File: 222533-60-0.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 2H-Indol-2-one, 1,3-dihydro-3-(3-methyl-2-butenyl)-1-(phenylmethyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: 2H-Indol-2-one, 1,3-dihydro-3-(3-methyl-2-butenyl)-1-(phenylmethyl)-(222533-60-0)
• EPA Substance Registry System: 2H-Indol-2-one, 1,3-dihydro-3-(3-methyl-2-butenyl)-1-(phenylmethyl)-(222533-60-0)

Safety Data

• Hazardous Substances Data: 222533-60-0(Hazardous Substances Data)

Upstream product

• 100-39-0 benzyl bromide 
• 91-56-5 indole-2,3-dione 
• 1217-89-6 1-benzylisatin 
• 7135-32-2 1-benzylindolin-2-one 
• 870-63-3 prenyl bromide 

Downstream Products

• 1222484-95-8 C₂₆H₂₆N₂O₂ 
• 222533-64-4 (S)-1-benzyl-3-(3-methylbut-2-enyl)-3-(benzyloxycarbonylaminomethyl)-2-oxindole 
• 222533-65-5 (R)-1-benzyl-3-(hydroxymethyl)-3-(3-benzyloxycarbonylaminomethyl)-2-oxindole 
• 222533-68-8 (R)-1-benzyl-1'-benzyloxycarbonyl-5-methoxy-2-oxospiro(3H-indole-3,3'-pyrrolidine) 
• 222533-66-6 (3R)-1-benzyl-1'-benzyloxycarbonyl-2'-hydroxy-2-oxospiro(3H-indole-3,4'-pyrrolidine) 
• 222533-67-7 (R)-1-benzyl-1'-benzyloxycarbonyl-2-oxospiro(3H-indole-3,4'-pyrrolidine) 
• 222533-63-3 (S)-[1-benzyl-3-(3-methylbut-2-enyl)-2-oxo-2,3-dihydro-1H-indol-3-yl]acetic acid 
• 222533-62-2 (S)-1-benzyl-3-(3-methylbut-2-enyl)-3-(2-nitroethyl)-2-oxindole 
• 222533-59-7 (R)-1-benzyl-1'-methyl-5-methoxy-2-oxospiro(3H-indole-3,3'-pyrrolidine) 
• 799561-66-3 C₄₄H₄₈N₂O₄ 
• 799561-14-1 C₄₇H₅₂N₂O₄ 
• 222533-61-1 (S)-1-benzyl-3-(3-methylbut-2-enyl)-3-(2-nitrovinyl)-2-oxindole 

Relevant articles and documents

Molybdenum-catalyzed asymmetric allylic alkylation of 3-alkyloxindoles: Reaction development and applications

We report a full account of our work towards the development of Mo-catalyzed asymmetric allylic alkylation reactions with 3-alkyloxindoles as nucleophiles. The reaction is complementary to the Pd-catalyzed reaction with regard to the scope of oxindole nucleophiles. A number of 3-alkyloxindoles were alkylated successfully under mild conditions to give products with excellent yields and good-to-excellent enantioselectivities. Applications of this method to the preparation of indoline alkaloids such as (-)-physostigmine, ent-(-)-debromoflustramine B, and the indolinoquinoline rings of communesin B are reported.

Total Synthesis of (-)-horsfiline via asymmetric nitroolefination

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