2226-05-3

Basic information

• Product Name: Ethanol,2-(3,3-dimethylbicyclo[2.2.1]hept-2-ylidene)-
• Synonyms: D2,b-Norbornaneethanol, 3,3-dimethyl- (6CI,7CI,8CI);2-(3,3-Dimethylbicyclo[2.2.1]hept-2-ylidene)ethanol; 8-Camphenemethanol; NSC18920
• CAS NO: 2226-05-3
• Molecular Formula: C₁₁H₁₈O
• Molecular Weight: 166.26
• EINECS: 218-755-1
• Mol File: 2226-05-3.mol
• Article Data: 1

Chemical Properties

• Boiling Point: 242.8°Cat760mmHg
• Flash Point: 108.9°C
• Appearance: /
• Density: 1.049g/cm³
• Vapor Pressure: 0.00566mmHg at 25°C
• Refractive Index: 1.571
• PKA: 14.74±0.10(Predicted)
• CAS DataBase Reference: Ethanol,2-(3,3-dimethylbicyclo[2.2.1]hept-2-ylidene)-(CAS DataBase Reference)
• NIST Chemistry Reference: Ethanol,2-(3,3-dimethylbicyclo[2.2.1]hept-2-ylidene)-(2226-05-3)
• EPA Substance Registry System: Ethanol,2-(3,3-dimethylbicyclo[2.2.1]hept-2-ylidene)-(2226-05-3)

Safety Data

• Hazardous Substances Data: 2226-05-3(Hazardous Substances Data)

Usage

InChI:InChI=1/C11H18O/c1-11(2)9-4-3-8(7-9)10(11)5-6-12/h5,8-9,12H,3-4,6-7H2,1-2H3/b10-5-

Upstream product

• 2226-03-1 1-acetoxy-2-(3,3-dimethyl-[2]norbornyliden)-ethane 
• 50-00-0 formaldehyd 
• 79-92-5 camphene 
• 79-92-5 (+)-camphene 
• 35836-73-8 (1R)-(-)-nopol 
• 75-36-5 acetyl chloride 
• 87405-14-9 Trifluoro-acetic acid 2-[3,3-dimethyl-bicyclo[2.2.1]hept-(2Z)-ylidene]-ethyl ester 
• 54766-92-6 3,3-Dimethylspiro(bicyclo<2.2.1>heptane-2,1'-cyclopropane) 
• 1600-27-7 mercury(II) diacetate 
• 508-32-7 tricyclene 

Downstream Products

• 2226-06-4 phthalic acid mono-[2-(3,3-dimethyl-[2]norbornyliden)-ethyl ester] 
• 13211-15-9 (+-)-camphenilone 
• 473-35-8 2-(3-carboxy-cyclopentyl)-2-methyl-propionic acid 
• 81374-87-0 2-hydroxycamphenilic acid 
• 144-62-7 oxalic acid 
• 15780-34-4 1-(3,3-Dimethyl-2-exo-norbornyl)-ethanone 
• 97845-97-1 (E)-Ethyl 4-<5-(2,2-dimethyl-3-norbornyliden)-2-methyl-1-pentenyl>benzoate 
• 97845-97-1 (Z)-Ethyl 4-<5-(2,2-dimethyl-3-norbornyliden)-2-methyl-1-pentenyl>benzoate 
• 97846-01-0 (E)-Ethyl <5-(2,2-dimethyl-3-norbornyl)-2-methyl-1-pentenyl>benzoate 
• 97846-01-0 (Z)-Ethyl <5-(2,2-dimethyl-3-norbornyl)-2-methyl-1-pentenyl>benzoate 
• 2226-08-6 3-Hydroxyethyl-2,2-dimethyl-norbornan 
• 473-35-8 (+/-)-camphenic acid 

Relevant articles and documents

Heterolytic Cleavage of Homoallylic Alcohols: Part III - Synthesis and Reactions of Spiro(bicycloheptane-2,1'-cyclopropane). Derivatives with Electrophiles

Spiro(bicycloheptane-2,1'-cyclopropane) derivatives (6, 7 and 8) have been synthesised by cyclopropanation of suitable camphenes.A by-product formed along with 7 during Simmons-Smith reaction with 6-acetoxycamphene, has been assigned the brendanol structure (22).Treatment of 6, 7 and 8 with mercuric salts causes 1,3-cleavage of cyclopropane rings which in the case of 7 and 8 triggers fragmentation and leads to the formation of diene-aldehyde (20).