15780-34-4

Basic information

• Product Name: Ethanone, 1-(3,3-dimethylbicyclo[2.2.1]hept-2-yl)-, exo-
• CAS NO: 15780-34-4
• Molecular Formula: C11H18O
• Molecular Weight: 166.263
• Mol File: 15780-34-4.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Ethanone, 1-(3,3-dimethylbicyclo[2.2.1]hept-2-yl)-, exo-(CAS DataBase Reference)
• NIST Chemistry Reference: Ethanone, 1-(3,3-dimethylbicyclo[2.2.1]hept-2-yl)-, exo-(15780-34-4)
• EPA Substance Registry System: Ethanone, 1-(3,3-dimethylbicyclo[2.2.1]hept-2-yl)-, exo-(15780-34-4)

Safety Data

• Hazardous Substances Data: 15780-34-4(Hazardous Substances Data)

Upstream product

• 15780-45-7 (+/-)-1-(3,3-dimethyl-norborn-5-ene-2-endo-yl)-ethanone 
• 38359-48-7 ω-methyl camphene 
• 542-92-7 cyclopenta-1,3-diene 
• 15780-34-4 1-(3,3-Dimethyl-bicyclo<2.2.1>hept-2-yl)ethanon 
• 141-79-7 4-methyl-pent-3-en-2-one 
• 66062-78-0 1-((1S,4R)-3,3-Dimethyl-bicyclo[2.2.1]hept-2-yl)-ethanol 
• 90275-75-5 ω-bromo-ω-methylcamphene 
• 6090-21-7 ω-bromomethylcamphene 
• 2226-05-3 2-(3,3-Dimethylbicyclo<2.2.1>hept-2-ylidene)ethanol 
• 54382-52-4 (E)-3-ethylidene-2,2-dimethylbicyclo<2.2.1>heptane 
• 67-56-1 methanol 
• 92214-46-5 ω-iodo-ω-methylcamphene 
• 85506-67-8 endo-2,2-dimethylbicyclo<2.2.1>heptane-3-carboxylic acid 
• 917-54-4 methyllithium 

Downstream Products

• 67519-00-0 2-exo-10-camphanoic acid 
• 15780-34-4 1-(3,3-Dimethyl-2-exo-norbornyl)-ethanone 
• 66062-78-0 exo-1-(3,3-Dimethyl-bicyclo<2.2.1>hept-2-yl)-ethanol 
• 515-28-6 (+/-)-2.2-Dimethyl-norbornanol-(3exo) 
• 18310-55-9 (3,3-dimethylbicyclo[2.2.1]heptan-2-yl)methanol 
• 78924-96-6 2-(3',3'-Dimethyl-2'-exo-norbornyl)-2-hydroxyessigsaeurebenzylester 
• 78925-02-7 ((1S,2R,4R)-3,3-Dimethyl-bicyclo[2.2.1]hept-2-yl)-hydroxy-acetyl chloride 
• 94201-14-6 4-(3,3-Dimethyl-2-exo-norbornyl)-2-methylbut-2-en-1-ol 
• 79861-75-9 1-(3,3-Dimethyl-2-exo-bicyclo<2.2.1>heptyl)-2-bromethanon 

Relevant articles and documents

CONFORMATION-SPECIFIC PHOTOCHEMISTRY IN ISOTROPIC LIQUID MEDIA: NORRISH TYPE II REACTIONS OF EPIMERIC 2-ACETYL-3,3-DIMETHYL NORBORNANES

The epimeric ketones 1 and 2 have been shown to display conformation-specific photobehaviour, especially in liquid media.

Photochemistry of Vinyl Halides: Part I - Radical Versus Ionic Photobehaviour of Some Vinyl Halides Based on Camphene

A systematic study of the photochemical behaviour of a group of vinyl halides (1-5) incorporating bicyclo(2.2.1)heptane skeleton is reported.The various parameters that control the formation of radical and ionic products have been investigated.The quenching and sensitization studies reveal that the radical products are derived from the triplet excited states whereas the corresponding singlet excited states may be responsible for the ionic products.The ground-state (silver ion-assisted) solvolytic reactivity pattern of these vinyl halides has been correlated for the first time with their photobehaviour.A plausible mechanism based on electron transfer concept has been proposed.