223691-88-1

Basic information

• Product Name: Benzene, 1-(1-ethenyl-1,5-dimethyl-4-hexenyl)-4-methoxy-
• CAS NO: 223691-88-1
• Molecular Formula: C17H24O
• Molecular Weight: 244.377
• Mol File: 223691-88-1.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: Benzene, 1-(1-ethenyl-1,5-dimethyl-4-hexenyl)-4-methoxy-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1-(1-ethenyl-1,5-dimethyl-4-hexenyl)-4-methoxy-(223691-88-1)
• EPA Substance Registry System: Benzene, 1-(1-ethenyl-1,5-dimethyl-4-hexenyl)-4-methoxy-(223691-88-1)

Safety Data

• Hazardous Substances Data: 223691-88-1(Hazardous Substances Data)

Upstream product

• 5720-07-0 4-methoxyphenylboronic acid 
• 91940-11-3 (3,7-dimethylocta-1,6-diene-3-sulfonyl)benzene 
• 1298119-35-3 tert-butyl (3,7-dimethylocta-1,6-dien-3-yl) carbonate 
• 53206-65-8 4-methoxy-α-(3-methylbut-2-enyl) acetophenone 
• 2065-66-9 methyl-triphenylphosphonium iodide 
• 850406-02-9 2-(4-methoxyphenyl)-2,6-dimethylhept-5-enal 
• 1530-33-2 isopropyltriphenylphosphonium bromide 
• 223691-84-7 4-(4-methoxyphenyl)-4-methyl-hex-5-en-1-al 
• 1779-49-3 Methyltriphenylphosphonium bromide 
• 16666-80-1 triphenylphosphonio-1-methylethanide 
• 401895-09-8 C₂₆H₃₂O₂ 
• 401895-11-2 C₁₉H₂₂N₂O₃S 
• 401895-13-4 toluene-4-sulfonic acid 3-(4-methoxy-phenyl)-3-methyl-cyclobutyl ester 
• 401895-07-6 1-methoxy-4-(3-methylhexa-1,5-dien-3-yl)benzene 

Downstream Products

• 349473-22-9 4-(5,7-dimethylocta-1,6-dien-4-yl)phenol 

Relevant articles and documents

Regioselective molybdenum-catalyzed allylic substitution of tertiary allylic electrophiles: Methodology development and applications

The first molybdenum-catalyzed allylic sulfonylation of tertiary allylic electrophiles is described. The method employs a readily accessible catalyst (Mo(CO)6/2,2′-bipyridine, both are commercially available) and represents the first example of the use of a group 6 transition metal-catalyst for allylic sulfonylation of substituted tertiary allylic electrophiles to form carbon-sulfur bonds. This atom economic and operationally simple methodology is characterized by its relatively mild conditions, wide substrate scope, and excellent regioselectivity profile, thus unlocking a new platform to forge sulfone moieties, even in the context of late-stage functionalization and providing ample opportunities for further derivatization through traditional Suzuki cross-coupling reactions.

A short synthesis of (±)-sporochnol A, a chemical fish deterrent from a Caribbean marine alga

A short formal synthesis of (±)-sporochnol A (1) is described. In this synthesis, the quaternary carbon center is formed by successive alkylations of the carbanion a to the nitrile in an arylacetonitrile derivative, followed by conversion of the nitrile g

Total synthesis of sporochnols, fish deterrents from a marine alga

Sporochnols, fish deterrents from a marine alga, were synthesized, using intramolecular C-H insertion of alkylidenecarbene as a key step to construct the chiral quaternary center.