225376-17-0

Basic information

• Product Name: 1-O-allyl-6-O-trityl-β-D-glucopyranoside
• Synonyms: 1-O-allyl-6-O-trityl-β-D-glucopyranoside
• CAS NO: 225376-17-0
• Molecular Weight: 462.543
• Mol File: 225376-17-0.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: 1-O-allyl-6-O-trityl-β-D-glucopyranoside(CAS DataBase Reference)
• NIST Chemistry Reference: 1-O-allyl-6-O-trityl-β-D-glucopyranoside(225376-17-0)
• EPA Substance Registry System: 1-O-allyl-6-O-trityl-β-D-glucopyranoside(225376-17-0)

Safety Data

• Hazardous Substances Data: 225376-17-0(Hazardous Substances Data)

Upstream product

• 492-61-5 β-D-glucose 
• 76-83-5 trityl chloride 
• 48149-74-2 allyl D-glucopyranoside 
• 2280-44-6 D-Glucose 
• 604-69-3 β-D-glucose pentaacetate 
• 2595-07-5 allyl β-D-glucopyranoside 

Downstream Products

• 225376-40-9 tert-Butyl-dimethyl-((2S,3R,4R,5R)-2,3,4,5-tetrakis-benzyloxy-6-trityloxy-hexyloxy)-silane 
• 225376-68-1 Trimethyl-((4S,5R,6R,7R)-4,5,6,7-tetrakis-benzyloxy-8-trityloxy-oct-2-ynyl)-silane 
• 225376-60-3 C₅₄H₅₀Br₂O₅ 
• 225376-34-1 (2R,3R,4R,5S)-3,4,5-Tris-benzyloxy-6-(tert-butyl-dimethyl-silanyloxy)-1-trityloxy-hexan-2-ol 
• 225376-54-5 (2R,3S,4R,5R)-2,3,4,5-Tetrakis-benzyloxy-6-trityloxy-hexanal 
• 225376-64-7 C₅₄H₅₀O₅ 
• 225376-47-6 (2S,3R,4R,5R)-2,3,4,5-Tetrakis-benzyloxy-6-trityloxy-hexan-1-ol 
• 225376-26-1 2,3,4-tri-O-benzyl-6-O-trityl-D-glucitol 
• 225376-09-0 (2S,3S,4R,5S)-2,3,4,5-Tetrakis-benzyloxy-8-trimethylsilanyl-oct-6-ynal 
• 225376-72-7 (2R,3R,4R,5S)-2,3,4,5-Tetrakis-benzyloxy-8-trimethylsilanyl-oct-6-yn-1-ol 
• 225376-18-1 allyl-2,3,4-tri-O-benzyl-6-O-trityl-β-D-glucopyranoside 

Relevant articles and documents

Synthesis of novel carbohydrate based pyridinium ionic liquids and cytotoxicity of ionic liquids for mammalian cells

The large pool of naturally occurring carbohydrates with their diversity in chirality and structure led to the idea of a systematic investigation of carbohydrate based ILs. To this end, we investigated the influence of different ether groups, mainly methyl or ethyl ether, on the secondary OH groups as well as different configurations on physical properties such as melting point, thermostability and especially the influence on cell toxicity. For this investigation we chose α- and β-methyl-, β-allyl- and β-phenyl d-glucopyranose as well as four 1-deoxy-pentoses. In order to be able to classify the results, more ionic liquids with different structural motives were examined for cytotoxicity. Here, we present data that confirm the biocompatibility of such ILs consisting of naturally occurring molecules or their derivatives. The synthesized carbohydrate based ILs were tested for their suitability as additives in coatings for medical applications such as drug-eluting balloons.

Probing myo-inositol 1-phosphate synthase with multisubstrate adducts

The synthesis of a series of carbohydrate-nucleotide hybrids, designed to be multisubstrate adducts mimicking myo-inositol 1-phosphate synthase first oxidative transition state, is reported. Their ability to inhibit the synthase has been assessed and resu

Diastereoselective Bromination of Allyl Glycosides Using Tetrabutylammonium Tribromide

Both (R) and (S)-2,3-dibromo-1-propanol with e.e. up to 60percent have been obtained by diastereoselective addition of Br2 to allyl glucosides and galactosides having only one unprotected hydroxyl group at C-2 or C-6 using tetrabutylammonium tribromide, followed by hydrolysis.The absolute configuration is shown to depend on the position of the free hydroxyl and on the configuration at the anomeric centre.