22726-00-7

Basic information

• Product Name: 3-Bromobenzamide
• Synonyms: TIMTEC-BB SBB009893;M-BROMOBENZAMIDE;3-BROMOBENZAMIDE;META-BROMOBENZAMIDE;Benzamide, 3-bromo-;Benzamide, m-bromo-;3-(Carbamoyl)bromobenzene;Bromophenyl formamide
• CAS NO: 22726-00-7
• Molecular Formula: C₇H₆BrNO
• Molecular Weight: 200.03
• Product Categories: blocks;Bromides;Carboxes;Aromatics;Aromatic Carboxylic Acids, Amides, Anilides, Anhydrides & Salts;Anilines, Amides & Amines;Bromine Compounds
• Mol File: 22726-00-7.mol
• Article Data: 70

Chemical Properties

• Melting Point: 156-159℃
• Boiling Point: 297.4 °C at 760 mmHg
• Flash Point: 134℃
• Appearance: White/Solid
• Density: 1.61
• Vapor Pressure: 0.00136mmHg at 25°C
• Refractive Index: 1.5500 (estimate)
• Storage Temp.: Sealed in dry,Room Temperature
• PKA: 15.38±0.50(Predicted)
• CAS DataBase Reference: 3-Bromobenzamide(CAS DataBase Reference)
• NIST Chemistry Reference: 3-Bromobenzamide(22726-00-7)
• EPA Substance Registry System: 3-Bromobenzamide(22726-00-7)

Safety Data

• Hazard Codes: Xi,Xn
• Statements: 22
• Hazardous Substances Data: 22726-00-7(Hazardous Substances Data)

Usage

General Description

3-Bromobenzamide is a chemical compound with the formula C7H6BrNO. As suggested by its name, it contains bromine, and forms part of the benzamide class of organic compounds, which contain a carboxamide group that's linked to a benzene ring. The properties of this aromatic compound include a molecular weight of 200.0 g/mol and a melting point that ranges between 155-157°C (311-314.6 F). It appears as a white to pale yellow crystalline solid and is mainly used as an intermediate in the preparation of other chemical products in industries.

InChI:InChI=1/C7H6BrNO/c8-6-3-1-2-5(4-6)7(9)10/h1-4H,(H2,9,10)

Upstream product

• 1711-09-7 3-bromobenzoyl chloride 
• 24398-88-7 ethyl 3-bromobenzoate 
• 86650-60-4 3-bromo-N-nitrobenzamide 
• 6952-59-6 3-cyanobromobenzene 
• 585-76-2 m-bromobenzoic acid 
• 3132-99-8 m-bromobenzoic aldehyde 
• 15852-73-0 (3-Bromophenyl)methanol 
• 591-17-3 meta-bromotoluene 
• 591-18-4 1-Bromo-3-iodobenzene 
• 201230-82-2 carbon monoxide 
• 51873-95-1 3-bromobenzaldehyde oxime 
• 2142-63-4 1-(3-Bromophenyl)ethanone 
• 18523-22-3 2,3'-dibromoacetophenone 
• 2039-86-3 3-bromostyrene 

Downstream Products

• 6952-59-6 3-cyanobromobenzene 
• 15852-73-0 (3-Bromophenyl)methanol 
• 33322-41-7 3-bromo-benzoic acid bromoamide 
• 10269-01-9 3-bromobenzylamine 
• 591-19-5 m-Bromoaniline 
• 57338-88-2 3-bromo-benzoic acid-[bis-(2-cyano-ethyl)-amide] 
• 4461-35-2 3-Bromo-benzoyl isocyanate 
• 86650-60-4 3-bromo-N-nitrobenzamide 
• 55-21-0 benzamide 
• 183557-81-5 3-morpholin-4-ylbenzamide 
• 681161-44-4 3′-hydroxy-(1,1′-biphenyl)-3-carboxamide 
• 868620-39-7 4-[(3-bromobenzoyl)amino]-1-methyl-3-propyl-1H-pyrazole-5-carboxamide 
• 935265-32-0 3-(2-(1-(tert-butyldimethylsilyloxy)-7-phenylheptyl)oxazol-5-yl)benzamide 
• 546141-08-6 URB597 

Relevant articles and documents

Highly efficient one-pot synthesis of primary amides catalyzed by scandium(III) triflate under controlled MW

The present Letter highlights a versatile synthetic protocol for the one-pot synthesis of primary amides employing scandium(III) triflate as a catalyst in water under controlled MW. This methodology offers excellent yields in shorter reaction times with enhanced selectivity.

Visible light-mediated synthesis of amides from carboxylic acids and amine-boranes

Here, a photocatalytic deoxygenative amidation protocol using readily available amine-boranes and carboxylic acids is described. This approach features mild conditions, moderate-to-good yields, easy scale-up, and up to 62 examples of functionalized amides with diverse substituents. The synthetic robustness of this method was also demonstrated by its application in the late-stage functionalization of several pharmaceutical molecules.

Efficient nitriding reagent and application thereof

The invention discloses an efficient nitriding reagent and application thereof, wherein the nitriding reagent comprises nitrogen oxide, an active agent, a reducing agent and an organic solvent. By applying the nitriding reagent, nitrogen-containing compounds such as amide, nitrile and the like can be produced, and the method is simple in condition, low in waste discharge amount and simple in reaction equipment.

Cu(II)–metformin immobilized on graphene oxide: an efficient and recyclable catalyst for the Beckmann rearrangement

Abstract: In this study, for the first time, the copper(II) nanoparticles (NPs) have been immobilized on metformin-functionalized graphene oxide and then its catalytic applications have been investigated in synthesis of amides from aldoximes (Beckmann rearrangement). The chemical structure of prepared catalyst has been characterized by various analyses like FT-IR, TGA, TEM, SEM, EDX, and ICP. All analyses confirm the successful and stable immobilization of copper NPs on functionalized graphene oxide. This synthesized heterogeneous nanocatalyst showed excellent catalytic activity with high product yields and short reaction times. Also, the suggested catalyst could be recycled ten times without a drastic decrease in its catalytic activity. Graphic abstract: [Figure not available: see fulltext.].