228123-21-5Relevant articles and documents
Preparation of TMS protected trifluoromethylated alcohols using trimethylamine N-oxide and trifluoromethyltrimethylsilane (TMSCHF3)
Prakash, G.K. Surya,Mandal, Mihirbaran,Panja, Chiradeep,Mathew, Thomas,Olah, George A.
, p. 61 - 63 (2003)
A catalytic trifluoromethylation of aldehydes using trimethylamine N -oxide and trifluoromethyltrimethylsilane (TMSCF3) is described. Aromatic, aliphatic and α,β-unsaturated aldehydes provided good to excellent yields of the corresponding trifl
Fe-catalyzed nucleophilic activation of c-si versus allylic C-O bonds: Catalytic trifluoromethylation of carbonyl groups versus tandem trifluormethylation-allylation of olefins
Klein, Johannes E. M. N.,Rommel, Susanne,Plietker, Bernd
supporting information, p. 5802 - 5810 (2015/01/16)
The nucleophilic ferrate salt Bu4N[Fe(CO)3(NO)] (TBA[Fe]) is able to catalyze the direct trifluoromethylation of aldehydes and ketones using Me3SiCF3 as a trifluoromethylating agent. Interception of the C-Si I-b
Solkane 365mfc is an environmentally benign alternative solvent for trifluoromethylation reactions
Kusuda, Akihiro,Kawai, Hiroyuki,Nakamura, Shuichi,Shibata, Norio
supporting information; experimental part, p. 1733 - 1735 (2011/03/19)
Solkane 365mfc is introduced for the first time as a new, environmentally benign alternative solvent for nucleophilic trifluoromethylation reactions. The Royal Society of Chemistry 2009.
