228123-22-6Relevant articles and documents
One-pot synthesis of α-trifluoromethylstyrenes from aryl ketones and the Ruppert–Prakash reagent
Dilman, Alexander D.,Levin, Vitalij V.
, p. 684 - 685 (2021/11/26)
A new synthesis of α-trifluoromethylstyrenes from aromatic ketones and (trifluoromethyl) trimethylsilane is described. The reaction involves nucleophilic trifluoromethylation and elimination of trimethylsilanol, which are performed within one reaction fla
Cs2CO3-initiated trifluoro-methylation of chalcones and ketones for practical synthesis of trifluoromethylated tertiary silyl ethers
Dong, Cheng,Bai, Xing-Feng,Lv, Ji-Yuan,Cui, Yu-Ming,Cao, Jian,Zheng, Zhan-Jiang,Xu, Li-Wen
, (2017/06/08)
It was found that 1,2-trifluoromethylation reactions of ketones, enones, and aldehydes were easily accomplished using the Prakash reagent in the presence of catalytic amounts of cesium carbonate, which represents an experimentally convenient, atom-economi
Fe-catalyzed nucleophilic activation of c-si versus allylic C-O bonds: Catalytic trifluoromethylation of carbonyl groups versus tandem trifluormethylation-allylation of olefins
Klein, Johannes E. M. N.,Rommel, Susanne,Plietker, Bernd
supporting information, p. 5802 - 5810 (2015/01/16)
The nucleophilic ferrate salt Bu4N[Fe(CO)3(NO)] (TBA[Fe]) is able to catalyze the direct trifluoromethylation of aldehydes and ketones using Me3SiCF3 as a trifluoromethylating agent. Interception of the C-Si I-b
