22829-35-2

Basic information

• Product Name: trans-Ni(Cl)(H)(PCy₃)2
• CAS NO: 22829-35-2
• Molecular Weight: 656.018
• Mol File: 22829-35-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: trans-Ni(Cl)(H)(PCy₃)2(CAS DataBase Reference)
• NIST Chemistry Reference: trans-Ni(Cl)(H)(PCy₃)2(22829-35-2)
• EPA Substance Registry System: trans-Ni(Cl)(H)(PCy₃)2(22829-35-2)

Safety Data

• Hazardous Substances Data: 22829-35-2(Hazardous Substances Data)

Upstream product

• 96-10-6 diethylaluminium chloride 
• 2622-14-2 tricyclohexylphosphine 
• 115647-96-6 bis(tricyclohexylphosphine)nickel(II) dichloride 
• 930-81-4 1-norbornyllithium 

Downstream Products

• 25703-58-6 C₆H₅ONi(P(C₆H₁₁-cyclo)3)2H 
• 98240-78-9 {Cy₃PH}{(Cy₃P)NiCl₃} 
• 135396-17-7 Ni(H)(C₆H₅NC(O)OC₆H₅)(P(C₆H₁₁)3)2 
• 30376-82-0 trans-hydridoiodobis(tricyclohexylphosphine)nickel(II) 
• 100-66-3 methoxybenzene 

Relevant articles and documents

A 1-norbornene adduct of a transition metal and an electrochemical study of the bridgehead olefin complex

Treatment of a slurry of (PCy3)2NiCl2 in pentane with 1-norbornyllithium did not lead to the expected bis(1-norbornyl) nickel complex but instead led to formation of a 1-norbornene adduct, which has been structurally characterized. The X-ray data and the electrochemistry of the 1-norbornene complex suggest a metallacyclopropane extreme of olefin binding, stemming from the highly reactive nature of the bridgehead double bond.