96-10-6Relevant articles and documents
METHOD FOR MANUFACTURING DIALKYL ZINC AND DIALKYL ALUMINUM MONOHALIDE
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Page/Page column 8, (2011/02/25)
Disclosed is a manufacturing method for dialkyl zinc and dialkyl aluminum monohalide that makes it possible to efficiently manufacture both dialkyl zinc and dialkyl aluminum monohalide of high purity and at a high yield on an industrial scale with a single reaction from zinc chloride and trialkyl aluminum starting materials, while suppressing the production of precipitates in the reaction process and suppressing the adhesion of precipitates to the equipment and the admixture thereof into the product. The manufacturing method for dialkyl zinc and dialkyl aluminum monohalide is a dialkyl zinc and dialkyl aluminum monohalide manufacturing method that causes a reaction between zinc chloride and trialkyl aluminum, and uses trialkyl aluminum with a hydride concentration of 0.01 mass% to 0.10 mass%. Dialkyl zinc that contains essentially no aluminum is separated from the reactants, and then dialkyl aluminum monohalide that contains essentially no zinc is separated.
Effect of crystallization water and nature of an aluminum alkyl on the reduction of Eu3+ to Eu2+ in interaction of EuCl 3 ? 6H2O with Bu 3 i Al and Et3Al
Bulgakov,Kuleshov,Makhmutov
, p. 1342 - 1345 (2010/01/05)
Volumetric and photoluminescence analytical techniques were employed to study the effect of crystallization water and nature of an aluminum alkyl on the reduction of Eu3+ to Eu2+ in a heterophase interaction of EuCl3 ? 6H
Stereoselective olefin polymerization catalysts generated by the transfer-epimetalation of olefins or acetylenes with dialkyltitanium(IV) complexes: Three-membered metallocycles as proposed chiral sites
Eisch, John J.,Gitua, John N.
, p. 4172 - 4174 (2008/10/08)
Efficient transfer-epimetalations of simple olefins and acetylenes by R2TiL2 reagents (R = Bun, But; L = X) are readily achieved in THF at -78°C to generate titanacyclopropa(e)ne intermediates, readily capable o